692751
(R,R)-DACH-吡啶基 Trost 配体
95%
别名:
(–)-N,N′-(1R,2R)-1,2-二氨基环己烷二基双(2-吡啶甲酰胺)
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关于此项目
经验公式（希尔记法）:
C18H20N4O2
化学文摘社编号:
分子量:
324.38
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
InChI
1S/C18H20N4O2/c23-17(15-9-3-5-11-19-15)21-13-7-1-2-8-14(13)22-18(24)16-10-4-6-12-20-16/h3-6,9-14H,1-2,7-8H2,(H,21,23)(H,22,24)/t13-,14-/m1/s1
SMILES string
O=C(N[C@@H]1CCCC[C@H]1NC(=O)c2ccccn2)c3ccccn3
InChI key
BVYFDUZVVBXFBQ-ZIAGYGMSSA-N
assay
95%
form
solid
optical activity
[α]20/D -97.0°, c = 1 in methanol
mp
171-176 °C
functional group
amide
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Trost, B.M. et al.
Journal of the American Chemical Society, 124, 11616-11616 (2004)
Asymmetric Transition Metal-Catalyzed Allylic Alkylations.
Barry M. Trost et al.
Chemical reviews, 96(1), 395-422 (1996-02-01)
Trost, B.M. et al.
Aldrichimica Acta, 40, 59-59 (2007)
Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.
Barry M Trost et al.
Chemical reviews, 103(8), 2921-2944 (2003-08-14)
商品
Trost group pioneers C-2 symmetric ligands for rapid chiral product synthesis in asymmetric catalytic reactions.
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