双(3,5-二(三氟甲基)苯基)氯膦

Name: 双(3,5-二(三氟甲基)苯基)氯膦
Brand: ALDRICH

solid

别名:

P,P-Bis[3,5-bis(trifluoromethyl)phenyl]phosphinous chloride

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关于此项目

经验公式（希尔记法）:

C₁₆H₆ClF₁₂P

化学文摘社编号:

142421-57-6

分子量:

492.63

UNSPSC Code:

12352002

PubChem Substance ID:

329761683

NACRES:

NA.22

MDL number:

MFCD01630852

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产品名称

双(3,5-二(三氟甲基)苯基)氯膦,

SMILES string

FC(F)(F)c1cc(cc(c1)C(F)(F)F)P(Cl)c2cc(cc(c2)C(F)(F)F)C(F)(F)F

InChI

1S/C16H6ClF12P/c17-30(11-3-7(13(18,19)20)1-8(4-11)14(21,22)23)12-5-9(15(24,25)26)2-10(6-12)16(27,28)29/h1-6H

InChI key

DFZQEHBNAJGDCT-UHFFFAOYSA-N

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

mp

25-29 °C

functional group

phosphine

Quality Level

100

Application

Reactant for synthesis of:

Chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation
Ligands for palladium-catalyzed stereoselective allylation reactions
Ligands for enantioselective hydrogenations
Josiphos analog as catalyst for asymmetric hydrogenation
Ligands used in asymmetric hydrovinylation reactions

Reactant for enantioselective hydrogenation reactions catalyzed by Ru-(phosphine-oxazoline) complexes