DTBPF

Name: DTBPF
Brand: ALDRICH

solid

别名:

1,1′-双(二叔丁基膦)二茂铁

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关于此项目

经验公式（希尔记法）:

C₂₆H₄₄FeP₂

化学文摘社编号:

84680-95-5

分子量:

474.42

UNSPSC Code:

12350000

PubChem Substance ID:

329761720

NACRES:

NA.22

MDL number:

MFCD01630818

主要文件

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产品名称

DTBPF,

SMILES string

[Fe].CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.CC(C)(C)P([C]2[CH][CH][CH][CH]2)C(C)(C)C

InChI

1S/2C13H22P.Fe/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h2*7-10H,1-6H3;

InChI key

FPLSJBJGQLJLSV-UHFFFAOYSA-N

form

solid

reaction suitability

reaction type: Cross Couplings
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Indole Forming Reactions
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

mp

73-75 °C

functional group

phosphine

Quality Level

100

Application

形成二烯络合物；羰基插入；环加成；还原和脱氧。

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

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Rhodium-catalyzed direct C-H addition of 3,4-dihydroquinazolines to alkenes and their use in the total synthesis of vasicoline.

Sean H Wiedemann et al.

The Journal of organic chemistry, 71(5), 1969-1976 (2006-02-25)

The inter- and intramolecular couplings of unactivated alkenes to 3,4-dihydroquinazolines with a Rh(I) catalyst are reported. Coupling between olefins and NH-3,4-dihydroquinazoline was found to occur consecutively with heterocycle dehydrogenation in the presence of a Rh(I)/PCy3/HCl catalyst. The reaction was used

Sergeyev, S.; Hesse, M.

Synlett, 8, 1313-1313 (2002)

Darbasie, N. D.; Schnatter, W. F. K. et al.

Tetrahedron Letters, 47, 963-963 (2004)

A convenient one-pot procedure to afford bicyclic molecules by stereospecific iron carbonyl mediated [6 + 2] ene-type cyclization: a possible approach to gelsemine.

Anthony J Pearson et al.

Journal of the American Chemical Society, 125(44), 13326-13327 (2003-10-30)

A convenient one-pot procedure to prepare angularly substituted bicyclic and tricyclic molecules with excellent diastereoselectivity in good yield was developed, by Fe(CO)5 promoted cyclization. Three transformations (complexation, isomerization, and cyclization) were realized in a single operation. The product of this

DTBPF

solid

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关于此项目

主要文件

属性

产品名称

SMILES string

InChI

InChI key

form

reaction suitability

mp

functional group

Quality Level

相关类别

说明

Application

安全信息

pictograms

signalword

hcodes

pcodes

Hazard Classifications

target_organs

存储类别

wgk

flash_point_f

flash_point_c

ppe

文件

分析证书(COA)

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