695157
双(3,5-二甲苯基)磷
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关于此项目
经验公式（希尔记法）:
C16H19P
化学文摘社编号:
分子量:
242.30
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C16H19P/c1-11-5-12(2)8-15(7-11)17-16-9-13(3)6-14(4)10-16/h5-10,17H,1-4H3
SMILES string
Cc1cc(C)cc(Pc2cc(C)cc(C)c2)c1
InChI key
GPFIUEZTNRNFGD-UHFFFAOYSA-N
form
liquid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index
n20/D 1.599
density
1.017 g/mL at 25 °C
functional group
phosphine
Quality Level
Application
Bis(3,5-dimethylphenyl)phosphine can be used as a reactant to prepare:
- Iron(II) chiral diimine diphosphine complexes as catalysts for the asymmetric transfer hydrogenation of ketones.
- The complex of iridium with biphenol phosphite-phosphine bidentate ligand as an asymmetric catalyst for the hydrogenation of N-arylimines.
- Chiral phosphines with excellent stereoselectivity by 1, 4 addition reaction with α,β-unsaturated aldehydes using a palladium catalyst.
Legal Information
Kanata Chemical Technologies, Inc. 产品
Iridium Complexes with Phosphine- Phosphite Ligands. Structural Aspects and Application in the Catalytic Asymmetric Hydrogenation of N-Aryl Imines
Vargas S, et al.
Organometallics, 25(4), 961-973 (2006)
Stereoelectronic factors in iron catalysis: synthesis and characterization of aryl-substituted iron (II) carbonyl P-N-N-P complexes and their use in the asymmetric transfer hydrogenation of ketones
Sues PE, et al.
Organometallics, 30(16), 4418-4431 (2011)
Palladium-catalyzed 1, 4-addition of diarylphosphines to α, β -unsaturated aldehydes
Chen Y-R and Duan W-L
Organic Letters, 13(21), 5824-5826 (2011)
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