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Merck
CN

695262

2-二环己基磷-2′-甲基联苯

97%, solid

别名:

2-甲基-2′-二环己基膦联苯, MePhos, MebiphPCy2

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关于此项目

经验公式（希尔记法）:
C25H33P
化学文摘社编号:
251320-86-2
分子量:
364.50
UNSPSC Code:
12352002
PubChem Substance ID:
329761728
NACRES:
NA.22
MDL number:
MFCD03094577

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产品名称

2-二环己基磷-2′-甲基联苯, 97%

SMILES string

Cc1ccccc1-c2ccccc2P(C3CCCCC3)C4CCCCC4

InChI

1S/C25H33P/c1-20-12-8-9-17-23(20)24-18-10-11-19-25(24)26(21-13-4-2-5-14-21)22-15-6-3-7-16-22/h8-12,17-19,21-22H,2-7,13-16H2,1H3

InChI key

GPVWUKXZFDHGMZ-UHFFFAOYSA-N

assay

97%

form

solid

reaction suitability

reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

mp

105-109 °C

functional group

phosphine

Quality Level

100

相关类别

Application

了解有关Buchwald 膦配体的更多信息。

Legal Information

用法以美国专利 6307087 和 6395916 为准。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBJ3984
SHBH0238V
16196TK
13224MH

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David S Surry et al.
Angewandte Chemie (International ed. in English), 47(34), 6338-6361 (2008-07-30)
Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context. This Review discusses
David S Surry et al.
Chemical science, 2(1), 27-50 (2011-01-01)
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand
Ruben Martin et al.
Accounts of chemical research, 41(11), 1461-1473 (2008-07-16)
The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Recently, Pd-catalyzed carbon-carbon

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