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695467

1,3,5-三氮杂-7-磷杂三环[3.3.1.13.7]癸烷

Name: 1,3,5-三氮杂-7-磷杂三环[3.3.1.13.7]癸烷
Brand: ALDRICH

97%, solid

别名:

1,3,5-三氮杂-7-磷代金刚烷, NSC 266642, PTA

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关于此项目

经验公式（希尔记法）:

C₆H₁₂N₃P

化学文摘社编号:

53597-69-6

分子量:

157.15

UNSPSC Code:

12352005

PubChem Substance ID:

329761745

NACRES:

NA.22

MDL number:

MFCD00154905

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属性

产品名称

1,3,5-三氮杂-7-磷杂三环[3.3.1.13.7]癸烷, 97%

Quality Level

100

assay

97%

form

solid

reaction suitability

reagent type: ligand
reaction type: Hydroformylations, reagent type: ligand
reaction type: Hydrogenations, reagent type: ligand
reaction type: Morita-Baylis-Hillman Reactions, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

mp

244-250 °C

functional group

phosphine

SMILES string

C1N2CN3CN1CP(C2)C3

InChI

1S/C6H12N3P/c1-7-2-9-3-8(1)5-10(4-7)6-9/h1-6H2

InChI key

FXXRPTKTLVHPAR-UHFFFAOYSA-N

说明

General description

在空气中稳定的有机催化剂，可用于 Baylis-Hillman 转化

Application

The molecular mechanisms of antimetastatic ruthenium compounds explored through DIGE proteomics.：该研究通过差异凝胶电泳(DIGE)蛋白质组学研究钌化合物的抗转移作用。分析了钌络合物中的1,3,5-三氮杂-7-磷杂金刚烷及其生物作用，说明它的潜在抗癌性(Guidi et al., 2013)。
Synthesis, antimicrobial and antiproliferative activity of novel silver(I) tris(pyrazolyl)methanesulfonate and 1,3,5-triaza-7-phosphadamantane complexes.：该研究详述含有1,3,5-三氮杂-7-磷杂金刚烷的新型银络合物的合成，评估它们的抗菌和抗增殖活性，说明该化合物可用于生物医学领域(Pettinari et al., 2011)。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Trialkylphosphine for MBH Reactions

Amines and phosphines in nucleophilic catalysis are discussed, addressing the air sensitivity of phosphines.

相关内容

Frost Group – Professor Product Portal

The Frost group has a longstanding interest in aqueous phase organometallic chemistry with an emphasis on water-soluble phosphine ligands. One focus of this research group has been centered on the chemistry of the neutral, air stable, and water-soluble heterocyclic phosphine 1,3,5-Triaza-7-phosphaadamantane (PTA). PTA is a small phosphine ligands with a cone angle of ~103°. PTA binds metal centers quite strongly and is electronically more donating than PPh3. Ruthenium complexes of PTA have exhibited impressive anticancer activity. A wide variety of transition metal complexes of PTA have been utilized as catalysts for reactions such as hydrogenation, C-C bond forming reactions, atom transfer radical addition, and nitrile hydration.

Phosphine Ligand Application Guide

Hydroxyquinoline-derived anticancer organometallics: Introduction of amphiphilic PTA as an ancillary ligand increases their aqueous solubility.

William D J Tremlett et al.

Journal of inorganic biochemistry, 199, 110768-110768 (2019-07-30)

Organometallic compounds based on bioactive ligand systems have shown promising antiproliferative properties. The use of 8-hydroxyquinoline and its derivatives as bioactive ligands resulted in organometallic complexes with potent anticancer activity, but they lack aqueous solubility for further development. We report

He, Z. et al

Advanced Synthesis & Catalysis, 368, 413-413 (2006)

Phillips, A. D.; Gonsalvi, L. et al.

Coordination Chemistry Reviews, 248, 955-955 (2004)

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全球贸易项目编号

货号	GTIN
695467-2G	04061833550823
695467-500MG	04061833541098