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695467

1,3,5-三氮杂-7-磷杂三环[3.3.1.13.7]癸烷

Name: 1,3,5-三氮杂-7-磷杂三环[3.3.1.13.7]癸烷
Brand: ALDRICH

97%

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别名:

1,3,5-三氮杂-7-磷代金刚烷, NSC 266642, PTA

经验公式（希尔记法）:

C₆H₁₂N₃P

CAS号:

53597-69-6

分子量:

157.15

MDL编号:

MFCD00154905

PubChem化学物质编号:

329761745

NACRES:

NA.22

质量水平

100

检测方案

97%

形式

solid

反应适用性

reagent type: ligand
reaction type: Hydroformylations
reagent type: ligand
reaction type: Hydrogenations
reagent type: ligand
reaction type: Morita-Baylis-Hillman Reactions
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

mp

244-250 °C

官能团

phosphine

SMILES字符串

C1N2CN3CN1CP(C2)C3

InChI

1S/C6H12N3P/c1-7-2-9-3-8(1)5-10(4-7)6-9/h1-6H2

InChI key

FXXRPTKTLVHPAR-UHFFFAOYSA-N

正在寻找类似产品? Visit 产品对比指南

一般描述

在空气中稳定的有机催化剂，可用于 Baylis-Hillman 转化

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

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示例

T1503

货号

25G

包装规格/数量

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705578-5MG-PW

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MMYOMAG-74K-13

1000309185

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He, Z. et al

Advanced Synthesis & Catalysis, 368, 413-413 (2006)

Hydroxyquinoline-derived anticancer organometallics: Introduction of amphiphilic PTA as an ancillary ligand increases their aqueous solubility.

William D J Tremlett et al.

Journal of inorganic biochemistry, 199, 110768-110768 (2019-07-30)

Organometallic compounds based on bioactive ligand systems have shown promising antiproliferative properties. The use of 8-hydroxyquinoline and its derivatives as bioactive ligands resulted in organometallic complexes with potent anticancer activity, but they lack aqueous solubility for further development. We report

Phillips, A. D.; Gonsalvi, L. et al.

Coordination Chemistry Reviews, 248, 955-955 (2004)

Experimental and theoretical investigations of cyclometalated ruthenium(ii) complex containing CCC-pincer and anti-inflammatory drugs as ligands: synthesis, characterization, inhibition of cyclooxygenase and in vitro cytotoxicity activities in various cancer cell lines.

Leila Tabrizi et al.

Dalton transactions (Cambridge, England : 2003), 48(2), 728-740 (2018-12-19)

The new cyclometalated ruthenium(ii) complex, [Ru(CCC-Nap)(Ibu)(PTA)] was designed and synthesized using ibuprofen (Ibu), 1,3,5-triaza-7-phosphaadamantane (PTA) and CCC-pincer containing naproxen moiety (CCC-Nap) as ligands. The compounds were fully characterized by elemental analysis, FT-IR, multinuclear (1H, 13C, and 31P) NMR spectroscopy, and

Antiviral, Antibacterial, Antifungal, and Cytotoxic Silver(I) BioMOF Assembled from 1,3,5-Triaza-7-Phoshaadamantane and Pyromellitic Acid.

Sabina W Jaros et al.

Molecules (Basel, Switzerland), 25(9) (2020-05-07)

The present study reports the synthesis, characterization, and crystal structure of a novel bioactive metal-organic framework, [Ag4(µ-PTA)2(µ3-PTA)2(µ4-pma)(H2O)2]n·6nH2O (bioMOF 1), which was assembled from silver(I) oxide, 1,3,5-triaza-7-phosphaadamantane (PTA), and pyromellitic acid (H4pma). This product was isolated as a stable microcrystalline solid

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