698539
二水合双(对磺酰苯基)苯基膦 二钾盐
97%, solid
别名:
BSPP, 4,4′-(苯基亚膦基)二苯磺酸 二钾盐
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关于此项目
经验公式(希尔记法):
C18H13K2O6PS2 · 2H2O
化学文摘社编号:
分子量:
534.62
MDL编号:
UNSPSC代码:
12352002
PubChem化学物质编号:
NACRES:
NA.22
产品名称
二水合双(对磺酰苯基)苯基膦 二钾盐, 97%
质量水平
方案
97%
表单
solid
反应适用性
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
mp
98-102 °C
官能团
phosphine
SMILES字符串
O.O.[K+].[K+].[O-]S(=O)(=O)c1ccc(cc1)P(c2ccccc2)c3ccc(cc3)S([O-])(=O)=O
InChI
1S/C18H15O6PS2.2K.2H2O/c19-26(20,21)17-10-6-15(7-11-17)25(14-4-2-1-3-5-14)16-8-12-18(13-9-16)27(22,23)24;;;;/h1-13H,(H,19,20,21)(H,22,23,24);;;2*1H2/q;2*+1;;/p-2
InChI key
CVKCKLNGVYHFAX-UHFFFAOYSA-L
应用
二水合双(对磺酰苯基)苯基膦二钾盐(BSPP)是水溶性三芳基膦盐,可与银离子形成配位络合物,因此广泛用于银纳米颗粒(AgNP)的合成。
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Julian A Lloyd et al.
ACS nano, 11(2), 1604-1612 (2017-02-07)
Asymmetric nanoparticle trimers composed of particles with increasing diameter act as "plasmonic lenses" and have been predicted to exhibit ultrahigh confinement of electromagnetic energy in the space between the two smallest particles. Here we present an electrostatic self-assembly approach for
Photomediated synthesis of silver triangular bipyramids and prisms: the effect of pH and BSPP.
Zhang, Jian et al.
Journal of the American Chemical Society, 132(35), 12502-12510 (2010)
Mechanistic study of photomediated triangular silver nanoprism growth.
Xue, Can et al.
Journal of the American Chemical Society, 130(26), 8337-8344 (2008)
Speciation analysis of silver sulfide nanoparticles in environmental waters by magnetic solid-phase extraction coupled with ICP-MS.
Zhou, Xiaoxia et al.
Journal of Analytical Atomic Spectrometry, 31(11), 2285-2292 (2016)
Chirality of self-assembled metal-semiconductor nanostructures.
Sun, Maozhong et al.
Journal of Material Chemistry C, 2(15), 2702-2706 (2014)
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