69893
2-吗啉代乙基异腈
≥98.0% (GC)
别名:
4-(2-异氰基乙基)吗啉, MEI
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关于此项目
经验公式（希尔记法）:
C7H12N2O
化学文摘社编号:
分子量:
140.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4666990
Assay:
≥98.0% (GC)
Form:
liquid
Quality Level
assay
≥98.0% (GC)
form
liquid
refractive index
n20/D 1.469
bp
72-73 °C/0.7 mmHg (lit.)
density
1.017 g/mL at 20 °C (lit.)
functional group
amine, ether, isonitrile
storage temp.
−20°C
SMILES string
[C-]#[N+]CCN1CCOCC1
InChI
1S/C7H12N2O/c1-8-2-3-9-4-6-10-7-5-9/h2-7H2
InChI key
MFRZPLYKVDHOSN-UHFFFAOYSA-N
Application
2-吗啉代乙基异腈可用于合成：
它也用作有机发光二极管(OLED)用环金属铱配合物的配体。
- 氮无环卡宾(NAC)复合物，作为酚合成与炔烃水合的催化剂。
- 通过Ugi缩合反应形成各种咪唑并[1,2-a]吡啶和α-酰氨基酰胺。
- 具有重要治疗价值的2-氨基苯并噁唑和3-氨基苯并噁嗪。
它也用作有机发光二极管(OLED)用环金属铱配合物的配体。
Other Notes
多肽合成的强效偶联剂，与DCCI相比产率更高、消旋产物最少；类Passerini 反应试剂，生成α-羟基酰胺
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Nature, 578(7793), 82-93 (2020-02-07)
Cancer is driven by genetic change, and the advent of massively parallel sequencing has enabled systematic documentation of this variation at the whole-genome scale1-3. Here we report the integrative analysis of 2,658 whole-cancer genomes and their matching normal tissues across 38
J.-L. Fauchere
Helvetica Chimica Acta, 68, 770-770 (1985)
New and Easily Accessible Nitrogen Acyclic Gold (I) Carbenes: Structure and Application in the Gold-Catalyzed Phenol Synthesis as well as the Hydration of Alkynes.
Hashmi ASK, et al.
Advanced Synthesis & Catalysis, 352(8), 1315-1337 (2010)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 69893-50ML | 04061838136435 |
| 69893-10ML | 04061832794808 |