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经验公式(希尔记法):
C5H11NaO
化学文摘社编号:
分子量:
110.13
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
MDL number:
产品名称
叔戊醇钠 溶液, 1.4 M in THF
InChI
1S/C5H11O.Na/c1-4-5(2,3)6;/h4H2,1-3H3;/q-1;+1
SMILES string
[Na+].CCC(C)(C)[O-]
InChI key
CGRKYEALWSRNJS-UHFFFAOYSA-N
form
liquid
concentration
1.4 M in THF
refractive index
n20/D 1.415
density
0.904 g/mL at 25 °C
Quality Level
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signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Self-heat. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 1
flash_point_f
1.4 °F
flash_point_c
-17 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Brandon K Tate et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(28), 10160-10169 (2015-06-11)
Alkoxide-bridged disilver cations react with dihydrogen to form hydride-bridged cations, releasing free alcohol. Hydrogenolysis of neutral silver fluorides affords hydride-bridged disilver cations as their bifluoride salts. These reactions proceed most efficiently when the supporting ligands are expanded N-heterocyclic carbenes (NHCs)
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