703788
叔丁醇钠
99.9%
别名:
Sodium 2-methylpropan-2-olate, Sodium t-butoxide, Sodium tert-butanolate, Sodium tert-butylate
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关于此项目
线性分子式:
NaOC(CH3)3
化学文摘社编号:
分子量:
96.10
UNSPSC Code:
12352107
PubChem Substance ID:
NACRES:
NA.22
EC Number:
212-741-9
MDL number:
Beilstein/REAXYS Number:
3654215
Assay:
99.9%
Form:
powder
Application
叔丁醇钠可用作：
- 作为促进剂，促进芳香族化合物与卤代芳烃通过C-H键芳基化反应合成联芳基。
- 钯催化胺化反应中的碱。
- 作为碱，在钯催化剂存在的条件下，由未活化的芳基卤化物合成芳基 叔丁基醚。
- 参与 N-吲哚和 N-氮杂吲哚的去磺酰反应。
- 作为碱，用于烯烃和CO2合成丙烯酸钠。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1B
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 1
flash_point_f
57.2 °F
flash_point_c
14 °C
Synthesis of acrylates from olefins and CO2 using sodium alkoxides as bases
Manzini S, et al.
Catalysis Today, 281(10), 379-386 (2017)
tert-Butoxide-Mediated C-H Bond Arylation of Aromatic Compounds with Haloarenes
Yanagisawa S and Itami K
ChemCatChem, 3(5), 827-829 (2011)
Desulfonylation of Indoles and 7-Azaindoles Using Sodium tert-Butoxide
Chaulet C, et al.
Synlett, 2010(10), 1481-1484 (2010)
β-Hydrogen-Containing Sodium Alkoxides as Suitable Bases in Palladium-Catalyzed Aminations of Aryl Halides
Prashad M, et al.
The Journal of Organic Chemistry, 65(8), 2612-2614 (2000)
Palladium-catalyzed formation of aryl tert-butyl ethers from unactivated aryl halides
Parrish CA and Buchwald SL
The Journal of Organic Chemistry, 66(7), 2498-2500 (2001)
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