703788
叔丁醇钠
99.9%
别名:
Sodium 2-methylpropan-2-olate, Sodium t-butoxide, Sodium tert-butanolate, Sodium tert-butylate
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关于此项目
线性分子式:
NaOC(CH3)3
化学文摘社编号:
分子量:
96.10
UNSPSC Code:
12352107
PubChem Substance ID:
NACRES:
NA.22
EC Number:
212-741-9
MDL number:
Beilstein/REAXYS Number:
3654215
Assay:
99.9%
Form:
powder
Quality Level
assay
99.9%
form
powder
density
1.025 g/cm3 at 68 °F
SMILES string
[Na+].CC(C)(C)[O-]
InChI
1S/C4H9O.Na/c1-4(2,3)5;/h1-3H3;/q-1;+1
InChI key
MFRIHAYPQRLWNB-UHFFFAOYSA-N
Application
叔丁醇钠可用作：
- 作为促进剂，促进芳香族化合物与卤代芳烃通过C-H键芳基化反应合成联芳基。
- 钯催化胺化反应中的碱。
- 作为碱，在钯催化剂存在的条件下，由未活化的芳基卤化物合成芳基 叔丁基醚。
- 参与 N-吲哚和 N-氮杂吲哚的去磺酰反应。
- 作为碱，用于烯烃和CO2合成丙烯酸钠。
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signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1B
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 1
flash_point_f
57.2 °F
flash_point_c
14 °C
商品
Discover AdQPhos and its Pd pre-catalysts for selective α-arylation of diverse nucleophiles under mild aqueous conditions without hazardous solvents.
Synthesis of acrylates from olefins and CO2 using sodium alkoxides as bases
Manzini S, et al.
Catalysis Today, 281(10), 379-386 (2017)
tert-Butoxide-Mediated C-H Bond Arylation of Aromatic Compounds with Haloarenes
Yanagisawa S and Itami K
ChemCatChem, 3(5), 827-829 (2011)
Desulfonylation of Indoles and 7-Azaindoles Using Sodium tert-Butoxide
Chaulet C, et al.
Synlett, 2010(10), 1481-1484 (2010)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 703788-25G | 04061833390320 |
| 703788-5G | 04061833490716 |