704059
2,6-双((S)-4,5-二氢-4-苯乙基噁唑-2-基)吡啶
97%
别名:
(S)-BnCH2-PyBox, (S,S)-2,6-双(4-苄基甲基-2-噁唑啉-2-基)吡啶
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关于此项目
经验公式（希尔记法）:
C27H27N3O2
化学文摘社编号:
分子量:
425.52
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
产品名称
2,6-双((S)-4,5-二氢-4-苯乙基噁唑-2-基)吡啶, 97%
InChI
1S/C27H27N3O2/c1-3-8-20(9-4-1)14-16-22-18-31-26(28-22)24-12-7-13-25(30-24)27-29-23(19-32-27)17-15-21-10-5-2-6-11-21/h1-13,22-23H,14-19H2/t22-,23-/m0/s1
SMILES string
C(Cc1ccccc1)[C@H]2COC(=N2)c3cccc(n3)C4=N[C@@H](CCc5ccccc5)CO4
InChI key
IYRZZMJRGHERQU-GOTSBHOMSA-N
assay
97%
form
powder
optical activity
[α]22/D −75, c = 1 in chloroform
mp
154-158 °C
functional group
ether
phenyl
Quality Level
Application
用于仲烯丙基氯化物不对称 Negishi 交叉偶联反应的配体
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Sunghee Son et al.
Journal of the American Chemical Society, 130(9), 2756-2757 (2008-02-09)
Complementing previous advances in allylation chemistry, an effective nickel/Pybox catalyst for regioselective asymmetric Negishi cross-couplings of racemic secondary allylic chlorides with readily available organozinc halides has been developed. The method has been applied in two key steps of a formal
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