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Merck
CN

704628

R-(叔丁基甲基膦-二叔丁基膦甲烷)-η4-(1,5-环辛二烯)四氟硼酸铑(I)

96%

别名:

R[Rh(cod)TCFP]BF4

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关于此项目

经验公式（希尔记法）:
C22H44P2Rh
分子量:
473.44
NACRES:
NA.22
PubChem Substance ID:
329762467
UNSPSC Code:
12352002
MDL number:
MFCD11973806

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产品名称

R-(叔丁基甲基膦-二叔丁基膦甲烷)-η4-(1,5-环辛二烯)四氟硼酸铑(I), 96%

InChI

1S/C14H32P2.C8H12.BF4.Rh/c1-12(2,3)15(10)11-16(13(4,5)6)14(7,8)9;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11H2,1-10H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t15-;;;/m1.../s1

SMILES string

[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.CP(CP(C(C)(C)C)C(C)(C)C)C(C)(C)C

InChI key

CQCAQRWECWCUBU-JMJDVLNDSA-N

assay

96%

form

solid

mp

171-177 °C

functional group

phosphine

storage temp.

2-8°C

Quality Level

100

相关类别

Legal Information

与 Johnson Matthey 联合销售，仅供研究目的。

Application

R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η4-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate can be used:
  • In the asymmetric reduction of amines, ketones and unsaturated acids.
  • As a hydrogenation catalyst in the preparation of diastereomers of trifluorovaline.
  • As a catalyst in the olefin asymmetric hydrogenation.

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
67697LJ

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Stefan Kraft et al.
Journal of the American Chemical Society, 139(34), 11630-11641 (2017-08-12)
The asymmetric hydrogenation of tetrasubstituted olefins provides direct access to very useful biological molecules and intermediates. The development of the technology has been slow, due in part to the synthetic challenges involved in developing chiral catalysts for a successful asymmetric
Garrett Hoge et al.
Journal of the American Chemical Society, 126(19), 5966-5967 (2004-05-13)
A concise synthesis of both enantiomers of ligand 2 and rhodium complex 5 is presented. The crux of the synthesis is a chiral HPLC separation of the enantiomers of 4. Rhodium complex 5 possesses three hindered quadrants in the steric
Ilya D Gridnev et al.
Journal of the American Chemical Society, 130(8), 2560-2572 (2008-02-02)
The rhodium complex of (R)-(tert-butylmethylphosphino)(di-tert-butylphosphino)methane used in Rh-catalyzed asymmetric hydrogenation of representative substrates 3-14 demonstrated high catalytic activity coupled with wide scope and nearly perfect enantioselectivity. Mechanistic studies (NMR and DFT computations) were carried out in order to investigate the
Johann Moschner et al.
Chemical reviews, 119(18), 10718-10801 (2019-08-23)
Fluorine does not belong to the pool of chemical elements that nature uses to build organic matter. However, chemists have exploited the unique properties of fluorine and produced countless fluoro-organic compounds without which our everyday lives would be unimaginable. The
He-Ping Wu et al.
Organic letters, 6(20), 3645-3647 (2004-09-25)
[reaction: see text] A previously reported three-hindered quadrant chiral ligand and its corresponding rhodium complex provide high enantioselectivity for the asymmetric hydrogenation of beta-acetamido dehydroamino acid substrates. Both (E)- and (Z)-substrates are hydrogenated with high enantioselectivity in all of the

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