Quality Segment
assay
96%
form
solid
mp
171-177 °C
functional group
phosphine
storage temp.
2-8°C
SMILES string
[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.CP(CP(C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI
1S/C14H32P2.C8H12.BF4.Rh/c1-12(2,3)15(10)11-16(13(4,5)6)14(7,8)9;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11H2,1-10H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t15-;;;/m1.../s1
InChI key
CQCAQRWECWCUBU-JMJDVLNDSA-N
Application
R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η4-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate can be used:
- In the asymmetric reduction of amines, ketones and unsaturated acids.
- As a hydrogenation catalyst in the preparation of diastereomers of trifluorovaline.
- As a catalyst in the olefin asymmetric hydrogenation.
Legal Information
与 Johnson Matthey 联合销售，仅供研究目的。
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)