form
solid
InChI
1S/C10H8N4/c1-5-11-6-2-9(1)13-14-10-3-7-12-8-4-10/h1-8H
SMILES string
c1cc(ccn1)N=Nc2ccncc2
InChI key
XUPMSLUFFIXCDA-UHFFFAOYSA-N
mp
96-101 °C
Quality Level
General description
4,4′-偶氮吡啶是一种芳香杂环化合物，用作[HgI2(4,4′-偶氮吡啶)]n 络合物的配体。
Application
4,4′-偶氮吡啶可用于：
- 与Zn(NO3)2和1,4-苯二甲酸反应制备多孔配位聚合物(PCP)。
- 作为在Mitsunobu条件下将脂肪醇转化为二硫化物的反应试剂。
- 制备4,4′-偶氮吡啶-桥联双核锌(II)配合物。
制备用反应物：
试剂：
- 1,2-双（4-吡啶基）肼溶剂热原位还原反应制备柔性多孔配位聚合物
- 过渡金属羧酸团簇作为次级结构单元的金属有机骨架
- Mitsunobu 条件下的芳杂环偶氮化合物
- MnII、CoII 和 ZnII 配位聚合物
- 芳香族超分子作用的低维多孔配合物
试剂：
- 易化的 Mitsunobu 酯化反应
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Flexible porous coordination polymers constructed from 1, 2-bis (4-pyridyl) hydrazine via solvothermal in situ reduction of 4, 4′-azopyridine
Liu X, et al.
Dalton Transactions, 40(34), 8549-8554 (2011)
4, 4?-Azopyridine as an easily prepared and recyclable oxidant for synthesis of symmetrical disulfides from thiols or alkyl halides (tosylates)/thiourea}
Khalili, Dariush and Iranpoor
Journal of Sulfur Chemistry, 36, 544-555 (2015)
Heteroaromatic azo compounds as efficient and recyclable reagents for direct conversion of aliphatic alcohols into symmetrical disulfides
Iranpoor N, et al.
Tetrahedron Letters, 53(51), 6913-6915 (2012)
A novel 4, 4′-azopyridine-bridged binuclear zinc complex
Zhu L, et al.
Journal of Coordination Chemistry, 56(17), 1447-1453 (2003)
A novel HgI2 adduct with an azopyridine ligand: synthesis, structure and optical refractive effect of [HgI2 (4, 4?-azopyridine)] n
Niu, Yunyin and Song
CrystEngComm, 3, 152-154 (2001)
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