70863
1-丁基-2,3-二甲基咪唑四氟硼酸盐
≥97.0%
别名:
[BDMIM][BF4]
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关于此项目
经验公式(希尔记法):
C9H17BF4N2
化学文摘社编号:
分子量:
240.05
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
一般描述
1-Butyl-2,3-dimethylimidazolium tetrafluoroborate is a task-specific ionic liquid.
应用
[bdmim]BF4 can be used as a solvent when lipase needs to be recycled during lipase-catalyzed transesterification with vinyl acetate as acyl donor. The [bdmim]BF4/toluene biphasic solvent forms an efficient system for the Negishi cross-coupling reaction between aryl zinc halides and aryl iodides.
其他说明
离子液体,适用于强碱性环境,如羟醛缩合反应
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves
Stetter reaction in room temperature ionic liquids and application to the synthesis of haloperidol
Anjaiah, Siddam, Srivari Chandrasekhar, and Rene Gree
Advanced Synthesis & Catalysis, 346.11, 1329-1334 (2004)
Enzyme-catalyzed reactions in ionic liquids
Moon, Yun Hee, et al.
Korean Journal of Chemical Engineering, 23.2, 247-263 (2006)
Hydrolase-catalyzed Kinetic Resolution of 5-[4-(1-Hydroxyethyl) phenyl]-10, 15, 20-tris (pentafluorophenyl) porphyrin in Ionic Liquids
Ema, Tadashi, Tokuhiro Doi, and Takashi Sakai
Chemistry Letters (Jpn), 37.1, 90-91 (2007)
Self?Organization of Spherical, Core?Shell Palladium Aggregates by Laser?Induced and Thermal Decomposition of [Pd (PPh3) 4]
Ye, Enyi, et al.
Angewandte Chemie (International Edition in English), 118.7, 1138-1141 (2006)
The local structure of ionic liquids: cation?cation NOE interactions and internuclear distances in neat [BMIM][BF4] and [BDMIM][BF4]
Mele, Andrea, et al.
Angewandte Chemie (International Edition in English), 45.7, 1123-1126 (2006)
商品
Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.
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