70863
1-丁基-2,3-二甲基咪唑四氟硼酸盐
≥97.0%
别名:
[BDMIM][BF4]
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关于此项目
经验公式（希尔记法）:
C9H17BF4N2
化学文摘社编号:
分子量:
240.05
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
≥97.0%
Form:
liquid
Quality Level
assay
≥97.0%
form
liquid
impurities
≤1% water
mp
37 °C
density
1.198 g/mL at 20 °C (lit.)
SMILES string
F[B-](F)(F)F.CCCCn1cc[n+](C)c1C
InChI
1S/C9H17N2.BF4/c1-4-5-6-11-8-7-10(3)9(11)2;2-1(3,4)5/h7-8H,4-6H2,1-3H3;/q+1;-1
InChI key
VCAIYEJBOWHUGP-UHFFFAOYSA-N
General description
1-Butyl-2,3-dimethylimidazolium tetrafluoroborate is a task-specific ionic liquid.
Application
[bdmim]BF4 can be used as a solvent when lipase needs to be recycled during lipase-catalyzed transesterification with vinyl acetate as acyl donor. The [bdmim]BF4/toluene biphasic solvent forms an efficient system for the Negishi cross-coupling reaction between aryl zinc halides and aryl iodides.
Other Notes
离子液体，适用于强碱性环境，如羟醛缩合反应
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存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
商品
Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.
The local structure of ionic liquids: cation?cation NOE interactions and internuclear distances in neat [BMIM][BF4] and [BDMIM][BF4]
Mele, Andrea, et al.
Angewandte Chemie (International Edition in English), 45.7, 1123-1126 (2006)
1-Butyl-2, 3-dimethylimidazolium tetrafluoroborate: the most desirable ionic liquid solvent for recycling use of enzyme in lipase-catalyzed transesterification using vinyl acetate as acyl donor.
Itoh T, et al.
Journal of Molecular Catalysis. B, Enzymatic, 26(1), 41-45 (2003)
Stetter reaction in room temperature ionic liquids and application to the synthesis of haloperidol
Anjaiah, Siddam, Srivari Chandrasekhar, and Rene Gree
Advanced Synthesis & Catalysis, 346.11, 1329-1334 (2004)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 70863-50G-F | 04061833417515 |
| 70863-5G-F | 04061833449141 |