70869
1-丁基-2,3-二甲基咪唑六氟磷酸盐
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关于此项目
经验公式（希尔记法）:
C9H17F6N2P
化学文摘社编号:
分子量:
298.21
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
Assay:
≥97.0% (HPLC), ≥97.0%
Form:
liquid
InChI
1S/C9H17N2.F6P/c1-4-5-6-11-8-7-10(3)9(11)2;1-7(2,3,4,5)6/h7-8H,4-6H2,1-3H3;/q+1;-1
SMILES string
F[P-](F)(F)(F)(F)F.CCCCn1cc[n+](C)c1C
InChI key
JWFPQAXAGSAKRF-UHFFFAOYSA-N
assay
≥97.0% (HPLC), ≥97.0%
form
liquid
density
1.345 g/mL at 20 °C (lit.)
Application
1-Butyl-2,3-dimethylimidazolium hexafluorophosphate is an ionic liquid that can be used:
- As a green solvent in the separation of endosulfan from water.
- As a binder in the preparation of carbon paste electrode, applicable in the detection of adenosine-5′-triphosphate in injection samples.
- As a component of the biphasic medium along with toluene, used in norbornene ring-opening metathesis polymerization.
Physical form
离子液体
Other Notes
离子液体，适用于强碱性环境，如羟醛缩合和复分解反应
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Priya A Thomas et al.
International journal of molecular sciences, 12(6), 3989-3997 (2011-07-13)
The self-metathesis of methyl oleate and methyl ricinoleate was carried out in the presence of ruthenium alkylidene catalysts 1-4 in [bmim] and [bdmim][X] type ionic liquids (RTILs) (X = PF(6) (-), BF(4) (-) and NTf(2) (-)) using the gas chromatographic
S. Csihony et al.
New. J. Chem., 26, 1667-1667 (2002)
Sensitive Electrochemical Determination of Adenosine-5′-triphosphate with 1-Butyl-2, 3-dimethylimidazolium Hexafluorophosphate Based Carbon Paste Electrode
Wei L, et al.
International Journal of Electrochemical Science, 14(11), 10070-10078 (2019)
1-Butyl-2, 3-dimethylimidazolium hexafluorophosphate as a green solvent for the extraction of endosulfan from aqueous solution using supported liquid membrane
Pilli SR, et al.
Chemical Engineering Journal, 257, 56-65 (2014)
First ring-opening metathesis polymerization in an ionic liquid. Efficient recycling of a catalyst generated from a cationic ruthenium allenylidene complex
Csihony S, et al.
New. J. Chem., 26(11), 1667-1670 (2002)
商品
Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.
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