711772
1-丁基-3-甲基咪唑鎓三氟甲磺酸盐
97%
别名:
BMIM Otf
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关于此项目
经验公式（希尔记法）:
C9H15F3N2O3S
化学文摘社编号:
分子量:
288.29
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
1-丁基-3-甲基咪唑鎓三氟甲磺酸盐, 97%
InChI
1S/C8H15N2.CHF3O3S/c1-3-4-5-10-7-6-9(2)8-10;2-1(3,4)8(5,6)7/h6-8H,3-5H2,1-2H3;(H,5,6,7)/q+1;/p-1
SMILES string
[O-]S(=O)(=O)C(F)(F)F.CCCCn1cc[n+](C)c1
InChI key
FRZPYEHDSAQGAS-UHFFFAOYSA-M
assay
97%
form
liquid
impurities
≤0.5% water
refractive index
n20/D 1.434
density
1.292 g/mL at 20 °C (lit.)
functional group
fluoro
triflate
Quality Level
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Application
[bmim][OTf] can be used as:
- A glycosylation promoter in the synthesis of oligosaccharides from thiophenyl and trichloroacetimidate glycoside donors.
- A solvent for the extraction of sulfur and nitrogen containing aromatic organic compounds from aliphatic hydrocarbons.
- A reagent in the preparation of ion-conductive polymeric membranes.
- A dopant in the synthesis of poly (ethyl methacrylate) based polymer electrolytes to increase the ionic conductivity.
- A reaction medium to synthesize aryl ketones by Friedel–Crafts benzoylation of aryl compounds by using bismuth triflate as a catalyst.
General description
1-Butyl-3-methylimidazolium trifluoromethanesulfonate [bmim][OTf] is a versatile ionic liquid commonly used in synthetic chemistry.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
>212.0 °F
flash_point_c
> 100 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
A new application of Baylis?Hillman alcohols to a diastereoselective synthesis of 3-nitrothietanes.
Rai A and Yadav L D S
Tetrahedron, 68(11), 2459-2464 (2012)
[bmim][OTf]: a versatile room temperature glycosylation promoter.
Galan M C, et al.
Tetrahedron Letters, 50(4), 442-445 (2009)
Efficient Air?Stable Organometallic Low?Molecular?Mass Gelators for Ionic Liquids: Synthesis, Aggregation and Application of Pyridine?Bridged Bis (benzimidazolylidene)?Palladium Complexes.
Tu T, et al.
Chemistry?A European Journal , 15(8), 1853-1861 (2009)
Improvement of the Friedel-Crafts benzoylation by using bismuth trifluoromethanesulfonate in 1-butyl-3-methylimidazolium trifluoromethanesulfonate ionic liquid under microwave irradiation
Tran PH, et al.
Tetrahedron Letters, 55(1), 205-208 (2014)
Deep fuels desulfurization and denitrogenation using 1-butyl-3-methylimidazolium trifluoromethanesulfonate
Ke?dra-Krolik K, et al.
Energy & Fuels, 25(4), 1559-1565 (2011)
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