叔丁醇钡

Name: 叔丁醇钡
Brand: ALDRICH

85%

别名:

二叔丁醇钡

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所有图片(2)

About This Item

经验公式（希尔记法）:

C₈H₁₈BaO₂

CAS Number:

24363-36-8

分子量:

283.55

MDL编号:

MFCD00082644

UNSPSC代码:

12352001

PubChem化学物质编号:

329762972

NACRES:

NA.22

质量水平

100

方案

85%

表单

powder

mp

>200 °C

储存温度

2-8°C

SMILES字符串

CC(C)(C)O[Ba]OC(C)(C)C

InChI

1S/2C4H9O.Ba/c2*1-4(2,3)5;/h2*1-3H3;/q2*-1;+2

InChI key

SLPLCLDJTNLWPW-UHFFFAOYSA-N

一般描述

Barium tert-butoxide is a Brønsted base catalyst that can be used as a precursor of various barium catalysts like barium aryloxide. It can also be used in the preparation of barium diphenylmethanide, applicable in the organometallic chemistry.

应用

Barium tert-butoxide can be used:

As a catalyst along with various phenolic ligands in the aldol reactions of amides with aldehydes and ketones.
To prepare yttrium and copper metal complexes by reacting with Y(thd)₃ and Cu(thd)₂, where “thd” is 2,2,6,6-tetramethylheptane-3,5-dione.
As an initiator along with an alkyl lithium in the butadiene copolymerization reaction.
In the iridium catalyzed allylic alkylation of non-stabilized enolates.