717398
(S)[(Sp)-2-(二苯基膦)二茂铁基]-4-异丙基噁唑啉
97%
别名:
(Sp)-1-(二苯基膦)-2-[(4S)-4-异丙基-2-噁唑基]二茂铁
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选择尺寸
关于此项目
经验公式（希尔记法）:
C28H28FeNOP
化学文摘社编号:
分子量:
481.35
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
产品名称
(S)[(Sp)-2-(二苯基膦)二茂铁基]-4-异丙基噁唑啉, 97%
InChI
1S/C23H23NOP.C5H5.Fe/c1-17(2)21-16-25-23(24-21)20-14-9-15-22(20)26(18-10-5-3-6-11-18)19-12-7-4-8-13-19;1-2-4-5-3-1;/h3-15,17,21H,16H2,1-2H3;1-5H;/t21-;;/m1../s1
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.CC(C)[C@H]2COC(=N2)[C]3[CH][CH][CH][C]3P(c4ccccc4)c5ccccc5
InChI key
FELCHLOAEMNOQM-GHVWMZMZSA-N
assay
97%
form
solid
optical activity
[α]20/D 366°, c = 0.1 in chloroform
mp
158-162 °C
functional group
ether
phosphine
Quality Level
Legal Information
Kanata Chemical Technologies Inc. 授权销售，仅供研究使用。
Application
(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline can be used as a chiral ligand in the synthesis of rhodium, iridium, ruthenium, and osmium metal complexes.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Synthesis and structure of chiral-at-metal complexes with the ligand (S)-2-[(Sp)-2-(diphenylphosphino) ferrocenyl]-4-isopropyloxazoline
Carmona D, et al.
Journal of Organometallic Chemistry, 691(26), 5560-5566 (2006)
Octahedral ruthenium (II) complexes containing the chiral ligand (4S)-2-[(Sp)-2-(diphenylphosphino) ferrocenyl]-4-(isopropyl) oxazoline (FcPN). X-Ray crystal structures of fac-[RuCl2 (PMe3) 2 (FcPN)] and fac-[RuCl2 (dppm)(FcPN)](dppm= bis (diphenylphosphino)methane)
Gimeno J, et al.
Journal of Organometallic Chemistry, 637, 463-468 (2001)
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