718386
二异丁基-叔丁氧基氢化铝锂 溶液
0.25 M in THF/hexanes
别名:
LDBBA
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关于此项目
经验公式（希尔记法）:
C12H28AlLiO
化学文摘社编号:
分子量:
222.27
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
产品名称
二异丁基-叔丁氧基氢化铝锂 溶液, 0.25 M in THF/hexanes
InChI
1S/C4H9O.2C4H9.Al.Li.H/c1-4(2,3)5;2*1-4(2)3;;;/h1-3H3;2*4H,1H2,2-3H3;;;/q-1;;;;+1;
SMILES string
[Li+].CC(C)C[AlH-](CC(C)C)OC(C)(C)C
InChI key
HNIYOHKCLUHKGY-UHFFFAOYSA-N
form
liquid
reaction suitability
reagent type: reductant
concentration
0.25 M in THF/hexanes
density
0.795 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
Application
Lithiumdiisobutyl-tert-butoxyaluminum hydride solution can be used as a reducing agent for the reduction of:
- Aromatic and aliphatic nitriles to aldehydes.
- Aromatic and aliphatic esters to aldehydes.
- Tertiary amides to aldehydes.
signalword
Danger
Hazard Classifications
Aquatic Chronic 2 - Asp. Tox. 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react 2
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
法规信息
危险化学品
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