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Merck
CN

719447

XtalFluor-M®

别名:

Morpho-DAST 二氟锍鎓盐, N-(二氟-λ4-硫酮)氯吗啉鎓, 二氟(吗啉)四氟硼酸锍, 二氟-4-吗啉基四氟硼酸锍, 吗啉二氟锍鎓四氟硼酸盐

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关于此项目

经验公式(希尔记法):
C4H8BF6NOS
化学文摘社编号:
分子量:
242.98
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
Form:
solid
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form

solid

Quality Level

mp

117-126 °C

functional group

ether

storage temp.

−20°C

SMILES string

F[B-](F)(F)F.F\S(F)=[N+]1/CCOCC1

InChI

1S/C4H8F2NOS.BF4/c5-9(6)7-1-3-8-4-2-7;2-1(3,4)5/h1-4H2;/q+1;-1

InChI key

SOCYGFRGCVLCSU-UHFFFAOYSA-N

Application

方便的结晶高度化学选择性脱氧氟化试剂,具有广泛的底物范围

脱氧氟化试剂具有更好的安全性,不会产生腐蚀性 HF,使其适用于标准硼硅酸盐容器,并且不会与水剧烈反应

反应物用于:
  • 氟代二糖的制备

Legal Information

XtalFluor-M is a registered trademark of OmegaChem, Inc.


pictograms

Skull and crossbonesCorrosion

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B

supp_hazards

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

This is an article regarding XtalFluor-E® and XtalFluor-M®: Convenient, Crystalline Deoxofluorination Reagents.


Francis Beaulieu et al.
Organic letters, 11(21), 5050-5053 (2009-10-06)
Aminodifluorosulfinium tetrafluoroborate salts were found to act as efficient deoxofluorinating reagents when promoted by an exogenous fluoride source and, in most cases, exhibited greater selectivity by providing less elimination byproduct as compared to DAST and Deoxo-Fluor. Aminodifluorosulfinium tetrafluoroborates are easy
Alexandre L'heureux et al.
The Journal of organic chemistry, 75(10), 3401-3411 (2010-04-22)
Diethylaminodifluorosulfinium tetrafluoroborate (XtalFluor-E) and morpholinodifluorosulfinium tetrafluoroborate (XtalFluor-M) are crystalline fluorinating agents that are more easily handled and significantly more stable than Deoxo-Fluor, DAST, and their analogues. These reagents can be prepared in a safer and more cost-efficient manner by avoiding



全球贸易项目编号

货号GTIN
719447-250G04061833565148
719447-1KG04061826680742
719447-25G04061833565155
719447-5G04061833565162