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Merck
CN

722995

Sigma-Aldrich

4-氰基-4-(苯基羰基硫)戊酸

别名:

4-氰基-4-(硫代苯甲酰)戊酸

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关于此项目

经验公式(希尔记法):
C13H13NO2S2
化学文摘社编号:
分子量:
279.38
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.23
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表单

powder

质量水平

mp

94-98 °C

储存温度

2-8°C

SMILES字符串

CC(CCC(O)=O)(SC(=S)c1ccccc1)C#N

InChI

1S/C13H13NO2S2/c1-13(9-14,8-7-11(15)16)18-12(17)10-5-3-2-4-6-10/h2-6H,7-8H2,1H3,(H,15,16)

InChI key

YNKQCPNHMVAWHN-UHFFFAOYSA-N

一般描述

4-氰基-4-(苯基硫代甲酰硫基)戊酸是一种硫基链转移剂,为活性自由基聚合提供了高度控制。

应用

可控自由基聚合的RAFT剂;特别适用于甲基丙烯酸酯和甲基丙烯酰胺单体的聚合。

象形图

Exclamation mark

警示用语:

Warning

危险声明

预防措施声明

危险分类

Skin Sens. 1

储存分类代码

11 - Combustible Solids

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

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商品

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

RAFT(可逆加成断裂链转移)聚合是一种可逆的去活化自由基聚合(RDRP),是给自由基聚合赋予活性的通用方法之一。

RAFT polymerization offers living characteristics to radical polymerization, contributing versatility to reversible deactivation radical polymerization methods.

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

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实验方案

RAFT(可逆加成-断裂链转移)是一种活性自由基聚合反应,在有适合的连转移(RAFT)试剂存在下发生的非传统的取代单体自由基聚合反应。

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

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