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723142

三[2-(二甲氨基)乙基]胺

97%

别名:

Me6TREN

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关于此项目

经验公式（希尔记法）:
C12H30N4
化学文摘社编号:
33527-91-2
分子量:
230.39
NACRES:
NA.23
PubChem Substance ID:
329763980
UNSPSC Code:
12162002
MDL number:
MFCD00015607
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Quality Level

100

assay

97%

form

liquid

refractive index

n20/D 1.455

density

0.862 g/mL at 25 °C

SMILES string

CN(C)CCN(CCN(C)C)CCN(C)C

InChI

1S/C12H30N4/c1-13(2)7-10-16(11-8-14(3)4)12-9-15(5)6/h7-12H2,1-6H3

InChI key

VMGSQCIDWAUGLQ-UHFFFAOYSA-N

General description

三[2-(二甲基氨基)乙基]胺(Me6TREN)是形成四齿配体的脂肪族叔胺。这种成分主要用于原子转移自由基聚合(ATRP)。它是(2-氨基乙基)胺的六甲基衍生物，也称为trenMe。可通过修饰Ristempart合成制备这一成分。

Application

Me6TREN与铜化合物形成络合物，可用作金属酶氧化还原反应中的配体。
用于生产遥爪聚合物的原子转移自由基聚合反应（ATRP）配体。

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

219.9 °F - closed cup

flash_point_c

104.4 °C - closed cup

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCX2440
MKCT2984
MKCL7208
MKCC8502
MKBV7794V

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实验方案

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

商品

ATRP Ligands & Initiators: Clean Functional Polymers

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

Trigonal bipyramidal complexes of bivalent manganese, iron, and zinc with tris (2-dimethylaminoethyl) amine
Ciampolini Mt and Nardi N
Inorganic Chemistry, 5(7), 1150-1154 (1966)
Optimization of atom transfer radical polymerization using Cu (I)/tris (2-(dimethylamino) ethyl) amine as a catalyst
Queffelec J, et al.
Macromolecules, 33(23), 8629-8639 (2000)
Diminishing catalyst concentration in atom transfer radical polymerization with reducing agents
Matyjaszewski K, et al.
Proceedings of the National Academy of Sciences of the USA, 103(42), 15309-15314 (2006)
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货号GTIN
723142-1ML04061832861067