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Merck
CN

723142

三[2-(二甲氨基)乙基]胺

97%

别名:

Me6TREN

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关于此项目

经验公式（希尔记法）:
C12H30N4
化学文摘社编号:
33527-91-2
分子量:
230.39
NACRES:
NA.23
PubChem Substance ID:
329763980
UNSPSC Code:
12162002
MDL number:
MFCD00015607

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InChI

1S/C12H30N4/c1-13(2)7-10-16(11-8-14(3)4)12-9-15(5)6/h7-12H2,1-6H3

SMILES string

CN(C)CCN(CCN(C)C)CCN(C)C

InChI key

VMGSQCIDWAUGLQ-UHFFFAOYSA-N

assay

97%

form

liquid

refractive index

n20/D 1.455

density

0.862 g/mL at 25 °C

Quality Level

100

相关类别

General description

三[2-(二甲基氨基)乙基]胺(Me6TREN)是形成四齿配体的脂肪族叔胺。这种成分主要用于原子转移自由基聚合(ATRP)。它是(2-氨基乙基)胺的六甲基衍生物，也称为trenMe。可通过修饰Ristempart合成制备这一成分。

Application

Me6TREN与铜化合物形成络合物，可用作金属酶氧化还原反应中的配体。
用于生产遥爪聚合物的原子转移自由基聚合反应（ATRP）配体。

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

219.9 °F - closed cup

flash_point_c

104.4 °C - closed cup

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCX2440
MKCT2984
MKCL7208
MKCC8502
MKBV7794V

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Optimization of atom transfer radical polymerization using Cu (I)/tris (2-(dimethylamino) ethyl) amine as a catalyst
Queffelec J, et al.
Macromolecules, 33(23), 8629-8639 (2000)
Diminishing catalyst concentration in atom transfer radical polymerization with reducing agents
Matyjaszewski K, et al.
Proceedings of the National Academy of Sciences of the USA, 103(42), 15309-15314 (2006)
Trigonal bipyramidal complexes of bivalent manganese, iron, and zinc with tris (2-dimethylaminoethyl) amine
Ciampolini Mt and Nardi N
Inorganic Chemistry, 5(7), 1150-1154 (1966)
Tsarevsky, N. V.; Braunecker, W. A.; Brooks, S. J.; Matyjaszewski, K.
Marcromolecules, 39, 6817-6817 (2006)
Xia Song et al.
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Paclitaxel (PTX), a hydrophobic anticancer drug, is facing several clinical limitations such as low bioavailability and drug resistance. To solve the problems, a well-defined β-cyclodextrin-poly(N-isopropylacrylamide) star polymer was synthesized and used as a nanocarrier to improve the water solubility and
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