72575
(R)-(+)-2-[2-(二苯基膦)苯基]-4-异丙基-2-噁唑啉
≥97.0% (CHN)
别名:
(R)-(+)-2-[2-(二苯基膦)苯基]-4,5-二氢-4-异丙基-噁唑
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关于此项目
经验公式（希尔记法）:
C24H24NOP
化学文摘社编号:
分子量:
373.43
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
8156604
Quality Level
assay
≥97.0% (CHN)
form
powder
optical activity
[α]20/D +48±3°, c = 1.4% in chloroform
mp
85-90 °C
functional group
ether, phosphine
SMILES string
CC(C)[C@@H]1COC(=N1)c2ccccc2P(c3ccccc3)c4ccccc4
InChI
1S/C24H24NOP/c1-18(2)22-17-26-24(25-22)21-15-9-10-16-23(21)27(19-11-5-3-6-12-19)20-13-7-4-8-14-20/h3-16,18,22H,17H2,1-2H3/t22-/m0/s1
InChI key
OUQSAXROROGQEE-QFIPXVFZSA-N
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Other Notes
可与铱催化剂发生不对称烷基化反应；不对称还原反应的手性配体
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
相关内容
Andreas Pfaltz's chiral ligand designs, like semicorrins, pioneered bisoxazolines for widespread catalytic asymmetric synthesis.
A. Lightfoot et al.
Angewandte Chemie (International Edition in English), 110, 3047-3047 (1998)
J.P. Janssen, G. Helmchen
Tetrahedron Letters, 38, 8025 -8025 (1997)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 72575-500MG-F | 04061832625799 |
| 72575-100MG-F | 04061832625782 |