726508
(R)-(+)-氧化苯乙烯
ChiPros®, produced by BASF, ≥98%
别名:
(R)-(+)-环氧乙基苯, (R)-环氧苯乙烷
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关于此项目
经验公式（希尔记法）:
C8H8O
化学文摘社编号:
分子量:
120.15
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1984
产品名称
(R)-(+)-氧化苯乙烯, ChiPros®, produced by BASF, ≥98%
InChI key
AWMVMTVKBNGEAK-QMMMGPOBSA-N
SMILES string
C1O[C@@H]1c2ccccc2
InChI
1S/C8H8O/c1-2-4-7(5-3-1)8-6-9-8/h1-5,8H,6H2/t8-/m0/s1
assay
≥98%
≥98.0% (GC)
form
liquid
optical purity
enantiomeric excess: ≥98.0%
expl. lim.
~22 %
refractive index
n20/D 1.534 (lit.)
bp
89-90 °C/23 mmHg (lit.)
density
1.051 g/mL at 25 °C (lit.)
functional group
ether
phenyl
Quality Level
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Legal Information
ChiPros is a registered trademark of BASF SE
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Carc. 1B - Eye Irrit. 2
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
176.0 °F - closed cup
flash_point_c
80 °C - closed cup
法规信息
新产品
此项目有
Laurent Gaté et al.
Toxicology letters, 211(3), 211-219 (2012-04-18)
The cytogenetic alterations in leukocytes and the increased risk for leukemia, lymphoma, or all lymphohematopoietic cancer observed in workers occupationally exposed to styrene have been associated with its hepatic metabolisation into styrene-7,8-oxide, an epoxide which can induce DNA damages. However
Feng Yu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(50), 14234-14240 (2011-11-09)
In the presence of PhSiH(3) as the reductant, the combination of enantiomeric dipyridylphosphane ligands and Cu(OAc)(2)·H(2)O, which is an easy-to-handle and inexpensive copper salt, led to a remarkably practical and versatile chiral catalyst system. The stereoselective formation of a selection
Gary P Carlson
Drug and chemical toxicology, 34(4), 440-444 (2011-07-14)
Styrene is known to be hepatotoxic and pneumotoxic in rodents, and these adverse effects are related to its metabolism. Mice deficient in the enzymes responsible for both the activation and detoxification of styrene are useful in examining this relationship more
Alessandra Lattanzi et al.
Chirality, 22 Suppl 1, E130-E135 (2010-11-03)
Density Functional Theory (DFT) calculations of optical rotation (OR) and vibrational circular dichroism (VCD) have been used to assign the absolute configuration (AC) of a recently prepared (3-phenyloxirane-2,2-diyl)bis(phenylmethanone), 3, by asymmetric epoxidation of the corresponding 2-arylidene-1,3-diketone. The experimental OR at
Jung-Hee Woo et al.
Biotechnology letters, 35(4), 599-606 (2012-12-18)
A novel epoxide hydrolase (EHase) from polycyclic aromatic hydrocarbon (PAH)-degrading bacteria was identified and characterized. EHase activity was identified in four strains of PAH-degrading bacteria isolated from commercial gasoline and oil-contaminated sediment based on their growth on styrene oxide and
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