726508
(R)-(+)-氧化苯乙烯
ChiPros®, produced by BASF, ≥98%
别名:
(R)-(+)-环氧乙基苯, (R)-环氧苯乙烷
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关于此项目
经验公式（希尔记法）:
C8H8O
化学文摘社编号:
分子量:
120.15
Beilstein:
1984
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
≥98%
≥98.0% (GC)
表单
liquid
光学纯度
enantiomeric excess: ≥98.0%
expl. lim.
~22 %
折射率
n20/D 1.534 (lit.)
沸点
89-90 °C/23 mmHg (lit.)
密度
1.051 g/mL at 25 °C (lit.)
官能团
ether
phenyl
SMILES字符串
C1O[C@@H]1c2ccccc2
InChI
1S/C8H8O/c1-2-4-7(5-3-1)8-6-9-8/h1-5,8H,6H2/t8-/m0/s1
InChI key
AWMVMTVKBNGEAK-QMMMGPOBSA-N
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法律信息
ChiPros is a registered trademark of BASF SE
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Dermal - Carc. 1B - Eye Irrit. 2
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
176.0 °F - closed cup
闪点(°C)
80 °C - closed cup
法规信息
新产品
此项目有
Styrene-7,8-oxide.
Report on carcinogens : carcinogen profiles, 12, 391-392 (2011-08-25)
Wen-Jing Chen et al.
Bioresource technology, 115, 58-62 (2011-11-22)
The asymmetric hydrolysis of styrene oxide to (R)-1-phenyl-1,2-ethanediol using Mung bean epoxide hydrolases was, for the first time, successfully conducted in an ionic liquid (IL)-containing biphasic system. Compared to aqueous monophasic system, IL-based biphasic systems could not only dissolve the
Michel Oelschlägel et al.
Applied and environmental microbiology, 78(12), 4330-4337 (2012-04-17)
Styrene oxide isomerase (SOI) is involved in peripheral styrene catabolism of bacteria and converts styrene oxide to phenylacetaldehyde. Here, we report on the identification, enrichment, and biochemical characterization of a novel representative from the actinobacterium Rhodococcus opacus 1CP. The enzyme
Wen-Jing Chen et al.
Journal of biotechnology, 162(2-3), 183-190 (2012-09-22)
A comparative study was made of Mung bean epoxide hydrolases-catalyzed asymmetric hydrolysis of styrene oxide to (R)-1-phenyl-1,2-ethanediol in an n-hexane/buffer biphasic system containing various hydrophilic ionic liquids (ILs). Compared to the n-hexane/buffer biphasic system alone, addition of a small amount
David M Hodgson et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(35), 9731-9737 (2011-07-19)
Starting from readily available (S)-styrene oxide an asymmetric synthesis is described of the naturally occurring anti-HIV spirolactone (-)-hyperolactone C, which possesses adjacent fully substituted stereocenters. The key step involves a stereocontrolled Rh(II) -catalysed oxonium ylide formation-[2,3] sigmatropic rearrangement of an
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