727725
1-丁基-1-甲基吡咯烷三氟甲磺酸盐
95%
别名:
BMPyrrOTf
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关于此项目
经验公式（希尔记法）:
C10H20F3NO3S
化学文摘社编号:
分子量:
291.33
Beilstein:
9820503
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
≥95.0% (T)
95%
表单
liquid
杂质
≤0.3% water
官能团
fluoro
triflate
SMILES字符串
[O-]S(=O)(=O)C(F)(F)F.CCCC[N+]1(C)CCCC1
InChI
1S/C9H20N.CHF3O3S/c1-3-4-7-10(2)8-5-6-9-10;2-1(3,4)8(5,6)7/h3-9H2,1-2H3;(H,5,6,7)/q+1;/p-1
InChI key
WZJDNKTZWIOOJE-UHFFFAOYSA-M
应用
1-丁基-1-甲基吡咯三氟甲磺酸盐([BMPy][OTf])是一种离子液，可用作以下反应的溶剂：
([BMPy][OTf])还可用作超级电容器应用中的电解质。
- 铑催化的区域选择性加氢甲酰化反应。
- 直接不对称羟醛缩合反应。
- 燃料脱硫。
- 亲核芳香族取代反应。
([BMPy][OTf])还可用作超级电容器应用中的电解质。
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
此项目有
Ionic liquids as designer solvents for nucleophilic aromatic substitutions
Newington I, et al.
Organic Letters, 9(25), 5247-5250 (2007)
Ionic liquids in supercapacitors
Brandt A, et al.
Mrs Bulletin, 38(7), 554-559 (2013)
Hydroformylation of 1-hexene with rhodium in non-aqueous ionic liquids: how to design the solvent and the ligand to the reaction
Favre F, et al.
Chemical Communications (Cambridge, England), 1360-1361 (2001)
Andrzej Lewandowski et al.
Journal of solution chemistry, 42(2), 251-262 (2013-03-14)
The electrochemical behavior of cobaltocenium has been studied in a number of room temperature aprotic ionic liquids. Well defined, diffusion controlled, anodic and cathodic peaks were found for the Cc
An improved protocol for the direct asymmetric aldol reaction in ionic liquids, catalysed by onium ion-tagged prolines
Lombardo M, et al.
advanced synthesis and catalysis, 349(11-12), 2061-2065 (2007)
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