731110
二-正丁基镁 溶液
1 M in ether and hexanes
登录 查看组织和合同定价。
选择尺寸
关于此项目
线性分子式:
[CH3(CH2)3]2Mg
化学文摘社编号:
分子量:
138.53
UNSPSC Code:
26111700
NACRES:
NA.23
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3535184
InChI
1S/2C4H9.Mg/c2*1-3-4-2;/h2*1,3-4H2,2H3;
SMILES string
CCCC[Mg]CCCC
InChI key
ODHFJIDDBSDWNU-UHFFFAOYSA-N
form
solution
greener alternative product characteristics
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
concentration
1 M in ether and hexanes
density
0.736 g/mL at 25 °C
greener alternative category
正在寻找类似产品? 访问 产品对比指南
General description
Di-n-butylmagnesium solution may be prepared by hydrogenation of magnesium, followed by reacting it with 1-butene.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.
Application
Electrochemically inactive [Mg2(μ-Cl)3•6THF][C2H5AlCl3] crystal may be obtained from an electrolyte composed of Di-n-butylmagnesium and ethylaluminum dichloride. Di-n-butylmagnesium may be used in the carbon metallation of α-olefins. A study reports the possible use of the organometallic compound in the intercalation of magnesium and zinc into the layers of TiS2 or WO2Cl2. Interaction of lithium alkoxide with di-n-butylmagnesium was investigated.
signalword
Danger
target_organs
Central nervous system
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
-22.0 °F
flash_point_c
-30 °C
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 1 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
法规信息
监管及禁止进口产品
此项目有
Multivalent cation intercalation
Bruce PG, et al.
Solid State Ionics, 53-56(1), 351-355 (1992)
King RB
Organometallic Syntheses null
Chemical and physical evidence for metal?metal interchange between lithium alkoxides and di-n-butylmagnesium.
Micha Screttas M, et al.
Tetrahedron Letters, 43(27), 4871-4873 (2002)
Some novelties in olefin carbometallation assisted by alkyl-magnesium and-aluminium derivatives and catalyzed by zirconium and titanium complexes.
Dzhemilev UM and Vostrikova OS
Journal of Organometallic Chemistry, 285(1), 43-51 (1985)
Hee Soo Kim et al.
Nature communications, 2, 427-427 (2011-08-11)
Magnesium metal is an ideal rechargeable battery anode material because of its high volumetric energy density, high negative reduction potential and natural abundance. Coupling Mg with high capacity, low-cost cathode materials such as electrophilic sulphur is only possible with a
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持