[2-（二叔丁基膦基甲基）-6-（二乙基氨基甲基）吡啶]羰基氯氢化钌（II）

Name: [2-（二<I>叔</I>丁基膦基甲基）-6-（二乙基氨基甲基）吡啶]羰基氯氢化钌（II）
Brand: ALDRICH

powder

别名:

Milstein Catalyst Precursor, [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride

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关于此项目

经验公式（希尔记法）:

C₂₀H₃₆ClN₂OPRu

化学文摘社编号:

863971-62-4

分子量:

488.01

UNSPSC Code:

12352300

PubChem Substance ID:

329765059

NACRES:

NA.22

MDL number:

MFCD16038117

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产品名称

[2-（二叔丁基膦基甲基）-6-（二乙基氨基甲基）吡啶]羰基氯氢化钌（II）,

SMILES string

Cl[RuH].[C-]#[O+].CCN(CC)Cc1cccc(CP(C(C)(C)C)C(C)(C)C)n1

InChI

1S/C19H35N2P.CO.ClH.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;;/h11-13H,9-10,14-15H2,1-8H3;;1H;;/q;;;+1;/p-1

InChI key

RZCAJPSOQUIHSH-UHFFFAOYSA-M

form

powder

reaction suitability

core: ruthenium, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

Aligned,

General description

May contain up to 10% acetone and/or THF.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Precursor to active Ru catalyst for the dehydrogenative coupling of amines and alcohols to form amide bonds.

Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2