735906
溴化铜
AnhydroBeads™, -10 mesh, 99.99% trace metals basis
别名:
一溴化铜
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关于此项目
线性分子式:
CuBr
化学文摘社编号:
分子量:
143.45
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-131-6
MDL number:
Assay:
99.99% trace metals basis
Grade:
synthesis grade
Form:
beads
grade
synthesis grade
Quality Segment
product line
AnhydroBeads™
assay
99.99% trace metals basis
form
beads
reaction suitability
core: copper
impurities
≤150.0 ppm Trace Metal Analysis
particle size
-10 mesh
mp
504 °C (lit.)
density
4.71 g/mL at 25 °C (lit.)
application(s)
electroplating
material synthesis precursor
SMILES string
[Cu]Br
InChI
1S/BrH.Cu/h1H;/q;+1/p-1
InChI key
NKNDPYCGAZPOFS-UHFFFAOYSA-M
General description
Cuprous bromide may be prepared by the reduction of cupric bromide or CuSO4-NaBr. In the molten state, it is grayish brown /greenish brown in color.
Application
Some reported applications of copper bromide are:
Reductive homocoupling of α-bromo- α- chlorocarboxylates to dimethyl α, α′ dichlorosuccinate derivatives in presence of CuBr/LiOCH3 in methanol has been reported.
- catalyst in cross coupling reactions.
- co-catalyst in Sonogashira coupling.
- Lewis acid in enantioselective addition of alkynes.
- reducing agent, when complexed by three molecules of pyridine initiators for the controlled polymerization of styrene, methyl acrylate and methyl methacrylate.
Reductive homocoupling of α-bromo- α- chlorocarboxylates to dimethyl α, α′ dichlorosuccinate derivatives in presence of CuBr/LiOCH3 in methanol has been reported.
Legal Information
AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC
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Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable