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Merck
CN

736236

2-氰基丙基 N-甲基-N-(4-吡啶)氨基二硫代碳酸酯

97% (HPLC)

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关于此项目

经验公式(希尔记法):
C11H13N3S2
化学文摘社编号:
分子量:
251.37
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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Quality Level

assay

97% (HPLC)

form

solid

mp

97-102 °C

storage temp.

2-8°C

SMILES string

CN(C(=S)SC(C)(C)C#N)c1ccncc1

InChI

1S/C11H13N3S2/c1-11(2,8-12)16-10(15)14(3)9-4-6-13-7-5-9/h4-7H,1-3H3

InChI key

PYVIBYAVTHICFS-UHFFFAOYSA-N

Application

用于受控自由基聚合的可切换RAFT试剂。 中性形式非常适合乙烯基酯和乙烯基酰胺(LAM)的聚合,质子化形式非常适合苯乙烯丙烯酸酯和甲基丙烯酸酯(MAM)。 链转移剂(CTA)


pictograms

Health hazard

signalword

Danger

hcodes

Hazard Classifications

Resp. Sens. 1 - Skin Sens. 1

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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实验方案

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

商品

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

Universal (Switchable) RAFT agents allow for the polymerization of both less activated and more activated monomers and are ideal for the synthesis of well-defined block copolymers.


RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being



全球贸易项目编号

货号GTIN
EME00100-1G04061825104324
OTV000575-250MG04061832302775
736236-5G04061832978307
736236-1G04061826280706