737763
Fmoc-Pro-Bt
0.95
别名:
(S)-(9H-Fluoren-9-yl)methyl 2-(1H-benzo[d][1,2,3]triazole-1-carbonyl)pyrrolidine-1-carboxylate, (S)-N-Fmoc-2-(benzotriazolylcarbonyl)pyrrolidine
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关于此项目
经验公式（希尔记法）:
C26H22N4O3
化学文摘社编号:
分子量:
438.48
UNSPSC Code:
12352209
PubChem Substance ID:
NACRES:
NA.26
MDL number:
产品名称
Fmoc-Pro-Bt, 95%
SMILES string
O=C(OCC1c2ccccc2-c3ccccc13)N4CCC[C@H]4C(=O)n5nnc6ccccc56
InChI
1S/C26H22N4O3/c31-25(30-23-13-6-5-12-22(23)27-28-30)24-14-7-15-29(24)26(32)33-16-21-19-10-3-1-8-17(19)18-9-2-4-11-20(18)21/h1-6,8-13,21,24H,7,14-16H2/t24-/m0/s1
InChI key
ZTDUGEKWIJHWKX-DEOSSOPVSA-N
assay
95%
form
solid
mp
163-168 °C
application(s)
peptide synthesis
functional group
Fmoc
storage temp.
2-8°C
Application
Benzotriazole amino acids, or aminoacylbenzotriazolides, are versatile reagents for synthesizing peptides as well as their mimetics and conjugates. Benzotriazole amino acids have been used for the preparation of diverse derivatives including:
- Polypeptidal benzotriazolides
- Peptidomimetics, such as aminoxypeptides, depsipeptides and heterocyclic peptidomimetics
- Tagged peptides and peptidomimetics, particularly those with fluorescent labels
- N, O, S, and C linked peptide conjugates
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Katritzky, A. R.; Angrish, P.; Todadze, E.
Synlett, 2392-2411 (2009)
Katritzky, A. R.; Narindoshvili, T.; Angrish, P.
Synthesis, 2013-2022 (2008)
Hansen, F. K.; Beagle, L. K.; Todadze, E.; Katritzky, A. R.
Heterocycles, 515-526 (2012)
Abdelmajeid, A.; Tala, S. R.; Amine, M. S.; Katritzky, A. R.
Synthesis, 2995-3005 (2011)
Alan R Katritzky et al.
The Journal of organic chemistry, 74(22), 8690-8694 (2009-10-17)
N-(Pg-alpha-aminoxy acids) 1a-g are converted to N-(Pg-alpha-aminoxyacyl)benzotriazoles 2a-g, which react under mild conditions with amines, alpha-amino acids/alpha-dipeptides, and alpha-aminoxy acids to give aminoxyacyl amides 3a-g, (3e+3e'), and (3g+3g'), aminoxy hybrid peptides 4a-h, (4a+4a'), 6a-d, 9a-e, (9a+9a'), and (9b+9b'), and alpha-aminoxy
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