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738883

1-Methyl-2-azaadamantane-N-oxyl

Name: 1-Methyl-2-azaadamantane-<I>N</I>-oxyl
Brand: ALDRICH

97%

别名:

1-Me-AZADO

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关于此项目

经验公式（希尔记法）:

C₁₀H₁₆NO

化学文摘社编号:

872598-44-2

分子量:

166.24

MDL number:

MFCD34679793

UNSPSC Code:

12352000

PubChem Substance ID:

329765308

NACRES:

NA.22

Assay:

97%

Form:

solid

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属性

Quality Level

100

assay

97%

form

solid

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

87-93 °C

greener alternative category

Aligned,

storage temp.

2-8°C

SMILES string

CC12CC3CC(CC(C3)N1[O])C2

InChI

1S/C10H16NO/c1-10-5-7-2-8(6-10)4-9(3-7)11(10)12/h7-9H,2-6H2,1H3

InChI key

IBNXYCCLPCGKDM-UHFFFAOYSA-N

说明

General description

1-Methyl-2-azaadamantane-N-oxyl (1-Me-AZADO), a sterically less hindered nitroxyl radical, is widely used as catalyst. It is chemically stable and exhibits superior catalytic performance.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

1-Methyl-2-azaadamantane-N-oxyl (1-Me-AZADO) may be employed as catalyst for the aerobic oxidation of alcohols and sterically hindered alcohols.

Catalytic oxidant for greener oxidation of alcohols under aerobic, solvent-free conditions. Recoverable and recyclable.

Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation

Other Notes

2-Azaadamantane N-Oxyl (AZADO) and 1-Me-AZADO: Highly Efficient Organocatalysts for Oxidation of Alcohols.

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

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Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation.

Kuang Y, et al.

Green Chemistry, 13(7), 1659-1663 (2011)

全球贸易项目编号

货号	GTIN
738883-100MG	04061826549414
738883-25MG	04061826549421