740608
tert-Butyl (tert-butyldimethylsilyl)glyoxylate
97%
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经验公式（希尔记法）:
C12H24O3Si
化学文摘社编号:
分子量:
244.40
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
liquid
InChI
1S/C12H24O3Si/c1-11(2,3)15-9(13)10(14)16(7,8)12(4,5)6/h1-8H3
SMILES string
CC(C)(C)OC(=O)C(=O)[Si](C)(C)C(C)(C)C
InChI key
GGYHTNUVBJRLDM-UHFFFAOYSA-N
assay
97%
form
liquid
refractive index
n20/D 1.440
density
0.920 g/mL at 25 °C
functional group
ester
Application
Learn More at the Professor and Product Portal of Professor Jeffrey S. Johnson.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
190.9 °F
flash_point_c
88.3 °C
法规信息
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The Johnson group has developed a family of reagents that are useful for the modular preparation of highly substituted glycolic acid derivatives. Silyl glyoxylates are potent electrophiles by virtue of being α-dicarbonyls, and react with a variety of nucleophiles.
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