Merck
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文件

740810

Sigma-Aldrich

2-（十二烷基硫基硫代羰基硫基）-2-甲基丙酸五氟苯基酯

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经验公式（希尔记法）:
C23H31F5O2S3
CAS号:
1174764-26-1
分子量:
530.68
MDL编号:
MFCD22417193
PubChem化学物质编号:
329765442
NACRES:
NA.23

形式

liquid

杂质

4-5% pentafluorophenol

折射率

n20/D 1.512

密度

1.203 g/mL at 25 °C

储存温度

2-8°C

SMILES字符串

CCCCCCCCCCCCSC(=S)SC(C)(C)C(=O)Oc1c(F)c(F)c(F)c(F)c1F

InChI

1S/C23H31F5O2S3/c1-4-5-6-7-8-9-10-11-12-13-14-32-22(31)33-23(2,3)21(29)30-20-18(27)16(25)15(24)17(26)19(20)28/h4-14H2,1-3H3

InChI key

XBUCQRRMAZYXHN-UHFFFAOYSA-N

相关类别

一般描述

需要帮助选择正确的RAFT试剂？请查阅RAFT试剂与单体的相容性表。

应用

用于受控自由基聚合的RAFT试剂，特别适用于苯乙烯、丙烯酸酯、丙烯酰胺单体的聚合。链转移剂(CTA)

其他说明

该产品含有4-5%的五氟苯酚杂质。 该杂质通常不会干扰链转移剂

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Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being
RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)

商品

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The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

A Micro Review of Reversible Addition/Fragmentation Chain Transfer (RAFT) Polymerization

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

实验方案

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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