740845
5-[二（1-金刚烷基）膦]-1′,3′,5′-三苯基-1′H-[1,4′] 联吡啶
97%, solid
别名:
Ad-BGPhos, 5-[双（1-金刚烷基）膦]-1′,3′,5′-三苯基-1,4′-双-1H-吡唑, 金刚烷胺双苯酚
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关于此项目
经验公式（希尔记法）:
C44H47N4P
化学文摘社编号:
分子量:
662.84
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
5-[二（1-金刚烷基）膦]-1′,3′,5′-三苯基-1′H-[1,4′] 联吡啶, 97%
SMILES string
C1[C@@H]2C[C@@H]3C[C@H]1C[C@](C2)(C3)P(c4ccnn4-c5c(nn(-c6ccccc6)c5-c7ccccc7)-c8ccccc8)[C@@]9%10C[C@@H]%11C[C@@H](C[C@@H](C%11)C9)C%10
InChI
1S/C44H47N4P/c1-4-10-36(11-5-1)40-42(41(37-12-6-2-7-13-37)47(46-40)38-14-8-3-9-15-38)48-39(16-17-45-48)49(43-24-30-18-31(25-43)20-32(19-30)26-43)44-27-33-21-34(28-44)23-35(22-33)29-44/h1-17,30-35H,18-29H2/t30-,31+,32-,33-,34+,35-,43-,44-
InChI key
IHFBOUNFWVRWAQ-GOSCEEDCSA-N
assay
97%
form
solid
reaction suitability
reagent type: ligand
mp
295-300 °C
storage temp.
2-8°C
Quality Level
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Application
5-[二（1-金刚烷基）膦]-1′,3′,5′-三苯基-1′H-[1,4′] 联吡啶 (Ad-BippyPhos) 是催化芳基和杂芳基溴化物/氯化物与伯醇 C-O 偶联反应的有效配体。也可作为催化剂，通过将氟烷基胺与芳基溴化物和氯化物偶联合成氟化苯胺。
Other Notes
在 2-8 °C 下储存。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Gowrisankar, S.; et al.
ChemCatChem, 3, 1439-1441 (2011)
A general and efficient catalyst for palladium-catalyzed C? O coupling reactions of aryl halides with primary alcohols.
Gowrisankar S, et al.
Journal of the American Chemical Society, 132(33), 11592-11598 (2010)
Palladium-Catalyzed C?O Coupling of a Sterically Hindered Secondary Alcohol with an Aryl Bromide and Significant Purity Upgrade in the API Step.
Young I S, et al.
Organic Process Research & Development, 22(5), 585-594 (2018)
S. Gowrisankar, et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 2498-2502 (2012)
Palladium-catalyzed arylation of fluoroalkylamines.
Brusoe A T and Hartwig J F
Journal of the American Chemical Society, 137(26), 8460-8468 (2015)
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