Merck
CN

741698

Sigma-Aldrich

2-(十二烷基硫基硫代羰基硫基)-2-甲基丙酸3-叠氮基-1-丙醇酯

98% (HPLC)

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经验公式(希尔记法):
C20H37N3O2S3
分子量:
447.72
MDL编号:
PubChem化学物质编号:

质量水平

检测方案

98% (HPLC)

形式

liquid

折射率

n20/D 1.528

密度

1.058 g/mL at 25 °C

储存温度

2-8°C

SMILES字符串

CCCCCCCCCCCCSC(=S)SC(C)(C)C(=O)OCCCN=[N+]=[N-]

InChI

1S/C20H37N3O2S3/c1-4-5-6-7-8-9-10-11-12-13-17-27-19(26)28-20(2,3)18(24)25-16-14-15-22-23-21/h4-17H2,1-3H3

InChI key

HQKDQLOBIDMFQX-UHFFFAOYSA-N

一般描述

需要帮助选择正确的RAFT试剂?请查阅RAFT试剂与单体的相容性表

应用

用于受控自由基聚合的官能化RAFT试剂,特别适用于苯乙烯、丙烯酸酯、丙烯酰胺单体的聚合。叠氮化物基团可用于与多种炔烃官能化的生物分子偶联。链转移剂(CTA)。

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

商品

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

实验方案

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

An article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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