9-甲基-9H-芴-9-羰基氯

Name: 9-甲基-9<I>H</I>-芴-9-羰基氯
Brand: ALDRICH

≥99.0% (GC)

别名:

COgen, 9-Methylfluorene-9-carbonyl chloride

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关于此项目

经验公式（希尔记法）:

C₁₅H₁₁ClO

化学文摘社编号:

82102-37-2

分子量:

242.70

UNSPSC Code:

12352005

NACRES:

NA.22

PubChem Substance ID:

329765723

MDL number:

MFCD18839248

Beilstein/REAXYS Number:

5266487

Assay:

≥99.0% (GC)

Form:

solid

主要文件

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InChI

1S/C15H11ClO/c1-15(14(16)17)12-8-4-2-6-10(12)11-7-3-5-9-13(11)15/h2-9H,1H3

SMILES string

CC1(C(Cl)=O)c2ccccc2-c3ccccc13

InChI key

ZQYOOHGEBHBNTP-UHFFFAOYSA-N

assay

≥99.0% (GC)

form

solid

reaction suitability

reaction type: C-C Bond Formation

functional group

acyl chloride

Quality Level

100

Application

COGen is a simple alternative for carbon monoxide generation in the application of palladium-catalyzed carbonylation reactions. This reagent has proved to be applicable in a wide range of applications and is compatible with several building blocks in the formation of ketones, amides, esters, etc.

For more information please visit: Technology Spotlight, Professor Skrystrup PPP

Use with the COware Platform

Other Notes

Frequently Asked Questions are available for this Product.

pictograms

GHS05

signalword

Danger

hcodes

H314

pcodes

P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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[¹⁴C]-Carbon Monoxide

Journal of Labelled Compounds & Radiopharmaceuticals, 55, 411-418 (2012)

Palladium-catalyzed carbonylative α-arylation for accessing 1,3-diketones.

Thomas M Gøgsig et al.

Angewandte Chemie (International ed. in English), 51(3), 798-801 (2011-12-06)

Ex situ generation of stoichiometric and substoichiometric 12CO and 13CO and its efficient incorporation in palladium catalyzed aminocarbonylations.

Philippe Hermange et al.

Journal of the American Chemical Society, 133(15), 6061-6071 (2011-03-31)

A new technique for the ex situ generation of carbon monoxide (CO) and its efficient incorporation in palladium catalyzed carbonylation reactions was achieved using a simple sealed two-chamber system. The ex situ generation of CO was derived by a palladium

Carbonylative Heck reactions using CO generated ex situ in a two-chamber system.

Philippe Hermange et al.

Organic letters, 13(9), 2444-2447 (2011-04-08)

A carbonylative Heck reaction of aryl iodides and styrene derivatives employing a two-chamber system using a stable, crystalline, and nontransition metal based carbon monoxide source is reported. By applying near-stoichiometric amounts of the carbon monoxide precursor, an effective exploitation of

Korsager, S.;

Angewandte Chemie (International Edition in English) (2013)

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Application of Carbon Monoxide in Synthesis Made Simple and Safe by Prof. Skrydstrup and Coworkers

Studies in the field of carbonylation chemistry led to the discovery of a novel carbon monoxide (CO) delivery system.

SyTracks Carbon Monoxide Generator FAQs

What is COgen? What is COware? What is the SyTracks COgenerator system? And more questions answered.

9-甲基-9H-芴-9-羰基氯

≥99.0% (GC)

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关于此项目

主要文件

属性

InChI

SMILES string

InChI key

assay

form

reaction suitability

functional group

Quality Level

相关类别

说明

Application

Other Notes

安全信息

pictograms

signalword

hcodes

pcodes

Hazard Classifications

存储类别

wgk

flash_point_f

flash_point_c

文件

分析证书(COA)

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