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Merck
CN

745022

9-甲基-9H-芴-9-羰基氯

≥99.0% (GC)

别名:

COgen, 9-Methylfluorene-9-carbonyl chloride

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关于此项目

经验公式（希尔记法）:
C15H11ClO
化学文摘社编号:
82102-37-2
分子量:
242.70
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
329765723
MDL number:
MFCD18839248
Beilstein/REAXYS Number:
5266487

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产品名称

9-甲基-9H-芴-9-羰基氯, ≥99.0% (GC)

InChI

1S/C15H11ClO/c1-15(14(16)17)12-8-4-2-6-10(12)11-7-3-5-9-13(11)15/h2-9H,1H3

SMILES string

CC1(C(Cl)=O)c2ccccc2-c3ccccc13

InChI key

ZQYOOHGEBHBNTP-UHFFFAOYSA-N

assay

≥99.0% (GC)

form

solid

reaction suitability

reaction type: C-C Bond Formation

functional group

acyl chloride

Quality Level

100

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相关类别

Application

COGen is a simple alternative for carbon monoxide generation in the application of palladium-catalyzed carbonylation reactions. This reagent has proved to be applicable in a wide range of applications and is compatible with several building blocks in the formation of ketones, amides, esters, etc.

For more information please visit: Technology Spotlight, Professor Skrystrup PPP

Use with the COware Platform

Other Notes

Frequently Asked Questions are available for this Product.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCL8388
BCCM4551
BCCK4341
BCCC4751
BCCH2798

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[14C]-Carbon Monoxide
Journal of Labelled Compounds & Radiopharmaceuticals, 55, 411-418 (2012)
Palladium-catalyzed carbonylative α-arylation for accessing 1,3-diketones.
Thomas M Gøgsig et al.
Angewandte Chemie (International ed. in English), 51(3), 798-801 (2011-12-06)
Philippe Hermange et al.
Organic letters, 13(9), 2444-2447 (2011-04-08)
A carbonylative Heck reaction of aryl iodides and styrene derivatives employing a two-chamber system using a stable, crystalline, and nontransition metal based carbon monoxide source is reported. By applying near-stoichiometric amounts of the carbon monoxide precursor, an effective exploitation of
Dennis U Nielsen et al.
The Journal of organic chemistry, 77(14), 6155-6165 (2012-06-26)
A novel and general approach for (13)C(2)- and (2)H-labeled phenethylamine derivatives has been developed, based on a highly convergent single-step assembly of the carbon skeleton. The efficient incorporation of two carbon-13 isotopes into phenethylamines was accomplished using a palladium-catalyzed double
Philippe Hermange et al.
Journal of the American Chemical Society, 133(15), 6061-6071 (2011-03-31)
A new technique for the ex situ generation of carbon monoxide (CO) and its efficient incorporation in palladium catalyzed carbonylation reactions was achieved using a simple sealed two-chamber system. The ex situ generation of CO was derived by a palladium
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Skrydstrup Group – Professor Product Portal

The Skrydstrup group has developed reagents and glassware for carrying out transition metal catalyzed carbonylations in a simple and safe manner.

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