745146
9-甲基-9 H-芴-9-羰基-13氯化氯
≥97.0% (GC)
别名:
13COgen
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关于此项目
经验公式（希尔记法）:
13CC14H11ClO
CAS Number:
分子量:
243.69
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
同位素纯度
≥97.0%
质量水平
方案
≥97.0% (GC)
表单
solid
反应适用性
reaction type: C-C Bond Formation
官能团
acyl chloride
SMILES字符串
CC1(c2ccccc2-c3ccccc13)[13C](Cl)=O
InChI
1S/C15H11ClO/c1-15(14(16)17)12-8-4-2-6-10(12)11-7-3-5-9-13(11)15/h2-9H,1H3/i14+1
InChI key
ZQYOOHGEBHBNTP-UJKGMGNHSA-N
应用
COGen is a simple alternative for carbon monoxide generation in the application of palladium-catalyzed carbonylation reactions. This reagent has proved to be applicable in a wide range of applications and is compatible with several building blocks in the formation of ketones, amides, esters, etc.
For more information please visit: Technology Spotlight, Professor Skrystrup PPP
Use with the COware Platform
For more information please visit: Technology Spotlight, Professor Skrystrup PPP
Use with the COware Platform
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
其他说明
Frequently Asked Questions are available for this Product.
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
[14C]-Carbon Monoxide
Journal of Labelled Compounds & Radiopharmaceuticals, 55, 411-418 (2012)
Philippe Hermange et al.
Organic letters, 13(9), 2444-2447 (2011-04-08)
A carbonylative Heck reaction of aryl iodides and styrene derivatives employing a two-chamber system using a stable, crystalline, and nontransition metal based carbon monoxide source is reported. By applying near-stoichiometric amounts of the carbon monoxide precursor, an effective exploitation of
Dennis U Nielsen et al.
The Journal of organic chemistry, 77(14), 6155-6165 (2012-06-26)
A novel and general approach for (13)C(2)- and (2)H-labeled phenethylamine derivatives has been developed, based on a highly convergent single-step assembly of the carbon skeleton. The efficient incorporation of two carbon-13 isotopes into phenethylamines was accomplished using a palladium-catalyzed double
Zhuo Xin et al.
Organic letters, 14(1), 284-287 (2011-12-16)
The palladium-catalyzed alkoxycarbonylation of aryl bromides is described for the efficient preparation of tertiary esters. The protocol proved compatible with a wide variety of functionalized (hetero)aromatic bromides, as well as several different sterically hindered tertiary alcohols, affording the alkoxycarbonylated products
Palladium-catalyzed carbonylative α-arylation for accessing 1,3-diketones.
Thomas M Gøgsig et al.
Angewandte Chemie (International ed. in English), 51(3), 798-801 (2011-12-06)
商品
Studies in the field of carbonylation chemistry led to the discovery of a novel carbon monoxide (CO) delivery system.
What is COgen? What is COware? What is the SyTracks COgenerator system? And more questions answered.
相关内容
The Skrydstrup group has developed reagents and glassware for carrying out transition metal catalyzed carbonylations in a simple and safe manner.
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