Merck
CN

745944

Sigma-Aldrich

D102 Dye

95% (HPLC)

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经验公式(希尔记法):
C37H30N2O3S2
分子量:
614.78
PubChem化学物质编号:
NACRES:
NA.23

质量水平

检测方案

95% (HPLC)

形式

powder

mp

238-243 °C

λmax

499 nm in DMF

SMILES字符串

S=C(S/C1=C\C(C=C2)=CC3=C2N(C4=CC=C(C=C(C5=CC=CC=C5)C6=CC=CC=C6)C=C4)C7C3CCC7)N(CC(O)=O)C1=O

InChI

1S/C37H30N2O3S2/c40-35(41)23-38-36(42)34(44-37(38)43)22-25-16-19-33-31(21-25)29-12-7-13-32(29)39(33)28-17-14-24(15-18-28)20-30(26-8-3-1-4-9-26)27-10-5-2-6-11-27/h1-6,8-11,14-22,29,32H,7,12-13,23H2,(H,40,41)/b34-22-

InChI key

XGMCROHUTRXETK-VQNDASPWSA-N

一般描述

D102 Dye is a low cost indoline based organic dye that can be used as a photosensitizer. Its power conversion efficiency is over 4% with a strong absorption coefficient (55800 Lmol-1cm-1 at 490nm). It has a high extinction coefficient in comparison to the ruthenium dye. It can improve the performance of electrochemical devices.

应用

D102 Dye can be used as a sensitizing material that can be coated on the semiconducting electrode for the fabrication of metal-free dye sensitized solar cells.
Photosensitive Red dye having excellent photoelectric conversion efficiency as a metal-free dye. Efficiency of DSSC device - η > 5.4%
Cell area: 0.25 cm2 (0.5 cm × 0.5 cm)
TiO2 Thickness: 5 μm
TiO2: screen printing
Electrolyte: 0.1 M LiI; 0.05 M I2; 0.6 M Dimethyl propylimidazolium
Iodide; 0.05 M t-Butylpyridine in 3-Methoxypropionitrile
Light source: AM1.5
Counter Electrode: Pt/Cr spatter glass
Dye adsorption: 30 °C/ in 3 hr. (t-BuOH/acetonitrile soln.)

法律信息

Product of Mitsubishi Paper Mills; Ltd

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Highly efficient poly (3-hexylthiophene) based monolithic dye-sensitized solar cells with carbon counter electrode
Wang H, et al.
Energy & Environmental Science, 4(6), 2025-2029 (2011)
Metal-free indoline dye sensitized solar cells based on nanocrystalline Zn2SnO4
Huang L, et al.
Electrochemical Communications, 12(2), 319-322 (2010)
Highly efficient nanoporous TiO2-polythiophene hybrid solar cells based on interfacial modification using a metal-free organic dye
Zhu R, et al.
Advanced Materials, 21(9), 994-1000 (2009)
Schmidt-Mende; Lukas;
Advanced Materials, 17(7), 813-815 (2005)
Organic dye-sensitized ionic liquid based solar cells: remarkable enhancement in performance through molecular design of indoline sensitizers
Kuang D, et al.
Angewandte Chemie (International Edition in English), 120(10), 1949-1953 (2008)

商品

Dye-sensitized solar cells (DSCs) are 3rd generation solar cells combining the promise of high efficiency with low production costs.

While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm

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