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Merck
CN

746339

二氯三苯基膦[双（2-（乙硫基）乙基）胺]钌（II）

greener alternative

97%, solid

别名:

Ru-SNS catalyst

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关于此项目

经验公式（希尔记法）:
C26H34Cl2NPRuS2
化学文摘社编号:
1462397-86-9
分子量:
627.63
UNSPSC Code:
12161600
PubChem Substance ID:
329765759
NACRES:
NA.22
MDL number:
MFCD26960799

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产品名称

二氯三苯基膦[双（2-（乙硫基）乙基）胺]钌（II）, 97%

SMILES string

CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

InChI

1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2

InChI key

ZQGMNGJIEYHKBR-UHFFFAOYSA-L

assay

97%

form

solid

reaction suitability

core: ruthenium, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

300-310 °C

greener alternative category

Aligned,

Quality Level

100

相关类别

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters
Catalyst for the hydrogenation of esters to alcohols.

Other Notes

"The mer-SNS complexes form isomers in solution. This is due to the different arrangements of the SEt groups relative to the SNS ligand plane. Two of the isomers have eclipsed SEt groups (arranged on one side of the SNS plane), and the third isomer has staggered SEt groups (occupying the opposite sides of the SNS plane)."

Legal Information

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCR2408
MKCK5335
MKBQ2000V

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Denis Spasyuk et al.
Angewandte Chemie (International ed. in English), 52(9), 2538-2542 (2013-01-29)
Catalyst tune-up: A readily available, air-stable amino-sulfide catalyst, [RuCl(2)(PPh(3)){HN(C(2)H(4)SEt)(2)}], has been developed. This complex displays outstanding efficiency for the hydrogenation of a broad range of substrates with C=X bonds (esters, ketones, imines), as well as for the acceptorless dehydrogenative coupling

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Gusev Group – Professor Product Portal

Prof. Dmitry Gusev's research focuses on organometallic compounds for catalytic applications like hydrogenation and dehydrogenation reactions.

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