746339
二氯三苯基膦[双（2-（乙硫基）乙基）胺]钌（II）
97%, solid
别名:
Ru-SNS catalyst
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关于此项目
经验公式（希尔记法）:
C26H34Cl2NPRuS2
化学文摘社编号:
分子量:
627.63
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
二氯三苯基膦[双（2-（乙硫基）乙基）胺]钌（II）, 97%
Quality Segment
assay
97%
form
solid
reaction suitability
reagent type: catalyst, reagent type: catalyst
core: ruthenium
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
300-310 °C
greener alternative category
SMILES string
CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
InChI
1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2
InChI key
ZQGMNGJIEYHKBR-UHFFFAOYSA-L
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Application
Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.
Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters
Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters
Catalyst for the hydrogenation of esters to alcohols.
Other Notes
"The mer-SNS complexes form isomers in solution. This is due to the different arrangements of the SEt groups relative to the SNS ligand plane. Two of the isomers have eclipsed SEt groups (arranged on one side of the SNS plane), and the third isomer has staggered SEt groups (occupying the opposite sides of the SNS plane)."
Legal Information
This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable