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Merck
CN

746347

Dichlorotriphenylphosphine[2-(diphenylphosphino)-N-(2-pyridinylmethyl)ethanamine]ruthenium(II)

greener alternative

97%, solid

别名:

Ru-PNN catalyst

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关于此项目

经验公式(希尔记法):
C38H36Cl2N2P2Ru
化学文摘社编号:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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产品名称

Dichlorotriphenylphosphine[2-(diphenylphosphino)-N-(2-pyridinylmethyl)ethanamine]ruthenium(II), 97%

SMILES string

Cl[Ru]Cl.[H]N(CCP(C1=CC=CC=C1)C2=CC=CC=C2)CC3=NC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6

InChI

1S/C20H21N2P.C18H15P.2ClH.Ru/c1-3-10-19(11-4-1)23(20-12-5-2-6-13-20)16-15-21-17-18-9-7-8-14-22-18;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h1-14,21H,15-17H2;1-15H;2*1H;/q;;;;+2/p-2

InChI key

JFYJJNHKCBDTMZ-UHFFFAOYSA-L

assay

97%

form

solid

reaction suitability

core: ruthenium, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

275-295 °C

greener alternative category

Quality Level

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

From Esters to Alcohols and Back with Ruthenium and Osmium Catalysts

Legal Information

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

pictograms

Skull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Spasyuk, D.;
Angewandte Chemie (International Edition in English), 2772-2772 (2012)

相关内容

Prof. Dmitry Gusev's research focuses on organometallic compounds for catalytic applications like hydrogenation and dehydrogenation reactions.

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