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Merck
CN

748854

碘三甲基硅烷 溶液

1 M in dichloromethane

别名:

三甲基碘硅烷 溶液, TMSI, 碘代三甲硅烷

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关于此项目

经验公式(希尔记法):
C3H9ISi
分子量:
200.09
NACRES:
NA.22
UNSPSC Code:
12352101
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form

liquid

Quality Segment

reaction suitability

reactivity: alcohol reactive, reagent type: protection reagent

concentration

1 M in dichloromethane

refractive index

n20/D 1.433

density

1.334 g/mL at 25 °C

functional group

silyl

storage temp.

2-8°C

General description

Iodotrimethylsilane [(CH3)3SiI] is an important and versatile organosilicon reagent with wide applications in organic synthesis. It is used as a neutral nucleophilic reagent, trimethylsilylating agent, Lewis acid catalyst, reducing agent and dehydrating agent in many organic reactions.

Application

Iodotrimethylsilane can be used as:
  • A reagent in the hydroiodation of ynamides to yield the important building blocks (E)-α-iodoenamides.
  • A reagent in the synthesis of (1-iodovinyl) arenes by hydroiodation of trimethylsilyl ethynylarenes.



警示词

Danger

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

靶器官

Central nervous system

supp_hazards

存储类别

3 - Flammable liquids

怎么回事?

WGK 3

闪点 (F)

-23.8 °F

闪点 (°C)

-31 °C



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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