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Merck
CN

752940

(三甲基磷酰亚胺)乙腈配制溶液 溶液

0.5 M in THF

别名:

CMMP, 氰亚甲基三甲基磷烷 溶液

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关于此项目

经验公式(希尔记法):
C5H10NP
化学文摘社编号:
分子量:
115.11
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352000
MDL number:
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产品名称

(三甲基磷酰亚胺)乙腈配制溶液 溶液, 0.5 M in THF

InChI

1S/C5H10NP/c1-7(2,3)5-4-6/h5H,1-3H3

SMILES string

CP(C)(C)=CC#N

InChI key

KJFJIEHJCVSAKJ-UHFFFAOYSA-N

form

liquid

concentration

0.5 M in THF

density

0.896 g/mL at 25 °C

functional group

nitrile
phosphine

storage temp.

2-8°C

Quality Level

General description

(三甲基膦酰亚胺)乙腈是一种试剂,通常用于酯、N-Boc内酰胺、内酯和酰亚胺等具有较低反应性羧酸化合物通过Wittig烯烃化反应得到α,β-不饱和腈。它还可作为Mitsonobu反应的替代试剂,通过取代DEAD/PPh3以进行C-H和N-H键的烷基化反应。

Other Notes

如果观察到沉淀,请略微加热使其溶解

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-5.8 °F - closed cup

flash_point_c

-21.0 °C - closed cup

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Tetrahedron Letters, 41(2), 235-237 (2000)
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