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经验公式(希尔记法):
C5H10NP
化学文摘社编号:
分子量:
115.11
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352000
MDL number:
产品名称
(三甲基磷酰亚胺)乙腈配制溶液 溶液, 0.5 M in THF
InChI
1S/C5H10NP/c1-7(2,3)5-4-6/h5H,1-3H3
SMILES string
CP(C)(C)=CC#N
InChI key
KJFJIEHJCVSAKJ-UHFFFAOYSA-N
form
liquid
concentration
0.5 M in THF
density
0.896 g/mL at 25 °C
functional group
nitrile
phosphine
storage temp.
2-8°C
Quality Level
General description
(三甲基膦酰亚胺)乙腈是一种试剂,通常用于酯、N-Boc内酰胺、内酯和酰亚胺等具有较低反应性羧酸化合物通过Wittig烯烃化反应得到α,β-不饱和腈。它还可作为Mitsonobu反应的替代试剂,通过取代DEAD/PPh3以进行C-H和N-H键的烷基化反应。
Other Notes
如果观察到沉淀,请略微加热使其溶解
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-5.8 °F - closed cup
flash_point_c
-21.0 °C - closed cup
法规信息
危险化学品
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