756792
3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane
97%
别名:
DAPTA
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关于此项目
经验公式（希尔记法）:
C9H16N3O2P
化学文摘社编号:
分子量:
229.22
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
产品名称
3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane, 97%
InChI
1S/C9H16N3O2P/c1-8(13)11-3-10-4-12(9(2)14)7-15(5-10)6-11/h3-7H2,1-2H3
SMILES string
CC(=O)N1CN2CN(CP(C2)C1)C(C)=O
InChI key
MYJHMDGWZWBLCK-UHFFFAOYSA-N
assay
97%
form
solid
mp
183 °C (decomposition)
functional group
phosphine
Quality Level
Application
3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane is a phosphine ligand and acetylized derivative of 1,3,5-triaza-7-phosphaadamantane that can be used:
- As a ligand in the synthesis of diiron dithiolate complexes of Fe-only hydrogenase to improve the hydro- and protophilicity of the active site.
- To prepare (η6-arene)-ruthenium(II) complex, which is employed as a catalyst in the reduction of allylic alcohols.
- As a ligand in the synthesis of water-soluble cis- and trans-Pt(II) and Pd(II) metal complexes.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Wenlong Ma et al.
Cancer science, 109(5), 1710-1722 (2018-03-24)
Nasopharyngeal carcinoma (NPC) is etiologically associated with Epstein-Barr virus (EBV) infection and is known to be highly vascularized. Previous studies have suggested that EBV oncoproteins contribute to NPC angiogenesis. However, the regulatory network of EBV in angiogenesis still remains elusive.
An approach to water-soluble hydrogenase active site models: Synthesis and electrochemistry of diiron dithiolate complexes with 3, 7-diacetyl-1, 3, 7-triaza-5-phosphabicyclo [3.3. 1] nonane ligand (s)
Na Y, et al.
Journal of Organometallic Chemistry, 691(23), 5045-5051 (2006)
Yanfang Song et al.
Cancer research, 77(7), 1611-1622 (2017-01-14)
Mice housed in an enriched environment display a tumor-resistant phenotype due to eustress stimulation. However, the mechanisms underlying enriched environment-induced protection against cancers remain largely unexplained. In this study, we observed a significant antitumor effect induced by enriched environment in
Ruthenium-catalyzed reduction of allylic alcohols using glycerol as solvent and hydrogen donor
Diaz-Alvarez AE, et al.
Catalysis Communications, 13(1), 91-96 (2011)
A new water-soluble phosphine derived from 1, 3, 5-triaza-7-phosphaadamantane (PTA), 3, 7-diacetyl-1, 3, 7-triaza-5-phosphabicyclo [3.3. 1] nonane. Structural, bonding, and solubility properties
Darensbourg DJ, et al.
Organometallics, 23(8), 1747-1754 (2004)
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