756792
3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane
97%
别名:
DAPTA
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关于此项目
经验公式（希尔记法）:
C9H16N3O2P
化学文摘社编号:
分子量:
229.22
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
97%
表单
solid
mp
183 °C (decomposition)
官能团
phosphine
SMILES字符串
CC(=O)N1CN2CN(CP(C2)C1)C(C)=O
InChI
1S/C9H16N3O2P/c1-8(13)11-3-10-4-12(9(2)14)7-15(5-10)6-11/h3-7H2,1-2H3
InChI key
MYJHMDGWZWBLCK-UHFFFAOYSA-N
应用
3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane is a phosphine ligand and acetylized derivative of 1,3,5-triaza-7-phosphaadamantane that can be used:
- As a ligand in the synthesis of diiron dithiolate complexes of Fe-only hydrogenase to improve the hydro- and protophilicity of the active site.
- To prepare (η6-arene)-ruthenium(II) complex, which is employed as a catalyst in the reduction of allylic alcohols.
- As a ligand in the synthesis of water-soluble cis- and trans-Pt(II) and Pd(II) metal complexes.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Ruthenium-catalyzed reduction of allylic alcohols using glycerol as solvent and hydrogen donor
Diaz-Alvarez AE, et al.
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An approach to water-soluble hydrogenase active site models: Synthesis and electrochemistry of diiron dithiolate complexes with 3, 7-diacetyl-1, 3, 7-triaza-5-phosphabicyclo [3.3. 1] nonane ligand (s)
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