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Merck
CN

757349

Sigma-Aldrich

氟代碳酸乙烯酯

greener alternative

99%

别名:

4-氟-1,3-二氧戊环-2-酮, FEC

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关于此项目

经验公式(希尔记法):
C3H3FO3
化学文摘社编号:
分子量:
106.05
EC 号:
MDL编号:
UNSPSC代码:
26111700
PubChem化学物质编号:
NACRES:
NA.23
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质量水平

方案

99%

表单

solid

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

沸点

212 °C

mp

18-23 °C

密度

1.485 g/cm3

应用

battery manufacturing

环保替代产品分类

储存温度

2-8°C

SMILES字符串

FC1COC(=O)O1

InChI

1S/C3H3FO3/c4-2-1-6-3(5)7-2/h2H,1H2

InChI key

SBLRHMKNNHXPHG-UHFFFAOYSA-N

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应用

氟代碳酸乙烯酯(FEC)可用作形成电解液的助溶剂,能显示出2.5 Ah g−1的可逆容量。可以进一步用于制造锂离子电池。FEC能够形成纤薄、光滑且稳定的被动固体电解质界面(SEI)层,不溶于电解液,从而增强二次电池的循环效率和放电容量保持率。

象形图

Exclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1

储存分类代码

11 - Combustible Solids

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Chuanfang John Zhang et al.
Nature communications, 10(1), 849-849 (2019-02-23)
The ever-increasing demands for advanced lithium-ion batteries have greatly stimulated the quest for robust electrodes with a high areal capacity. Producing thick electrodes from a high-performance active material would maximize this parameter. However, above a critical thickness, solution-processed films typically
High performance silicon nanoparticle anode in fluoroethylene carbonate-based electrolyte for Li-ion batteries
Lin Y, et al.
Chemical Communications (Cambridge, England), 48(58), 7268-7270 (2012)
Ben Breitung et al.
Scientific reports, 7(1), 13010-13010 (2017-10-14)
Si holds great promise as an alloying anode material for Li-ion batteries with improved energy density because of its high theoretical specific capacity and favorable operation voltage range. However, the large volume expansion of Si during electrochemical reaction with Li
Fluoroethylene carbonate additives to render uniform Li deposits in lithium metal batteries
Zhang X, et al.
Advances in Functional Materials, 27(10), 1605989-1605989 (2017)
Yu-Ting Weng et al.
Nature communications, 10(1), 5824-5824 (2019-12-22)
High coulombic efficiency and dendrite suppression in carbonate electrolytes remain challenges to the development of high-energy lithium ion batteries containing lithium metal anodes. Here we demonstrate an ultrathin (≤100 nm) lithium-ion ionomer membrane consisting of lithium-exchanged sulfonated polyether ether ketone embedded

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