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Merck
CN

760110

4-氰基-4-[(十二烷基磺胺基硫代羰基)磺胺基]戊醇

别名:

十二烷基硫醇氰基硫醇

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关于此项目

经验公式(希尔记法):
C19H35NOS3
分子量:
389.68
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
MDL number:
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assay

≥96.5% (HPLC)

Quality Level

form

solid or liquid (Powder or Solid or Crystals or Chunk(s) or Semi-solid or Liquid)

storage temp.

2-8°C

SMILES string

CCCCCCCCCCCCSC(=S)SC(C)(CCCO)C#N

InChI

1S/C19H35NOS3/c1-3-4-5-6-7-8-9-10-11-12-16-23-18(22)24-19(2,17-20)14-13-15-21/h21H,3-16H2,1-2H3

InChI key

SAFBIHFUHZPVOZ-UHFFFAOYSA-N

General description

可逆加成-断裂链转移(RAFT)聚合是一种制备窄分布复杂结构聚合物的方法。4-氰基-4-[(十二烷基磺酰基硫代羰基)磺酰基] 戊醇是一种羟基官能化三硫代碳酸盐筏试剂。用作 RAFT 和开环聚合的双引发剂,以形成明确定义的嵌段共聚物。它们能很好地控制各种乙烯基单体的聚合。

Application

嵌段共聚物 RAFT 和开环聚合的引发剂—这些嵌段共聚物来自于乙烯、金属离子、丙烯酰胺和环状单体的乙烯单体。

Features and Benefits

水解稳定性好,适用于各种单体及反应条件。


pictograms

Skull and crossbones

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

No data available

flash_point_c

No data available



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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实验方案

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

商品

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.


Thiocarbonylthio compounds (SC (Z) SR) in free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization).
Chiefari, J., Mayadunne, R. T., Moad, C. L., Moad, G., Rizzardo, E., Postma, A., & Thang, S. H.
Macromolecules, 36(7), 2273-2283 (2003)
One-step synthesis of block copolymers using a hydroxyl-functionalized trithiocarbonate RAFT agent as a dual initiator for RAFT polymerization and ROP
Kang, H. U., Yu, Y. C., Shin, S. J., & Youk, J. H.
Journal of Polymer Science Part A: Polymer Chemistry, 51(4), 774-779 (2013)
RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)



全球贸易项目编号

货号GTIN
760110-5G04061832978598
760110-1G04061826281154