760838
烯丙基四异丙基亚磷酰胺
95%
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关于此项目
线性分子式:
[[(CH3)2CH]2N]2POCH2CH=CH2
化学文摘社编号:
分子量:
288.41
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Assay:
95%
Form:
liquid
产品名称
烯丙基四异丙基亚磷酰胺, 95%
InChI
1S/C15H33N2OP/c1-10-11-18-19(16(12(2)3)13(4)5)17(14(6)7)15(8)9/h10,12-15H,1,11H2,2-9H3
SMILES string
CC(C)N(C(C)C)P(OCC=C)N(C(C)C)C(C)C
InChI key
ZTEGHJIXOZLSOH-UHFFFAOYSA-N
assay
95%
form
liquid
refractive index
n20/D 1.466 (lit.)
n20/D 1.467
bp
114-117 °C/0.4 mmHg (lit.)
density
0.903 g/mL at 25 °C (lit.)
0.910 g/mL at 25 °C
storage temp.
2-8°C
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Application
Allyl tetraisopropylphosphorodiamidite may be used in the total synthesis of (−)-tetrahydrolipstatin, dolabelide C, (-)-salicylihalamides A and B.
Phosphitylation agent used in the preparation of oligonucleotides. Selective deallylation is accomplished by palladium catalysis.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
188.0 °F
flash_point_c
86.67 °C
法规信息
新产品
此项目有
A concise, phosphate-mediated approach to the total synthesis of (?)-tetrahydrolipstatin.
Venukadasula PK, et al.
Organic Letters, 12(7), 1556-1559 (2010)
Phosphate Tether-Mediated Approach to the Formal Total Synthesis of (?)-Salicylihalamides A and B.
Chegondi R, et al.
The Journal of Organic Chemistry, 76(10), 3909-3916 (2011)
Total synthesis of dolabelide C: a phosphate-mediated approach.
Hanson PR, et al.
The Journal of Organic Chemistry, 76(11), 4358-4370 (2011)
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