761052
1H-Imidazole-1-carboxylic acid-3-butenyl ester
97%
别名:
Heller-Sarpong Reagent-Homoallyl
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关于此项目
经验公式（希尔记法）:
C8H10N2O2
化学文摘社编号:
分子量:
166.18
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
方案
97%
表单
liquid
折射率
n20/D 1.488
密度
1.107 g/mL at 25 °C
官能团
allyl
储存温度
2-8°C
SMILES字符串
O=C(OCCC=C)N1C=CN=C1
InChI
1S/C8H10N2O2/c1-2-3-6-12-8(11)10-5-4-9-7-10/h2,4-5,7H,1,3,6H2
InChI key
BNGLJMQCDKTXTL-UHFFFAOYSA-N
应用
1H-Imidazole-1-carboxylic acid-3-butenyl ester can be used:
- To prepare bis-naphthyridine derived cyclic mismatch binding ligands (CMBLs) which exhibit DNA repeat binding properties.
- As a reagent in the chemoselective esterification of carboxylic acids.
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Skin Sens. 1
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
230.0 °F
闪点(°C)
110 °C
法规信息
新产品
Design and synthesis of cyclic Mismatch-Binding Ligands (CMBLs) with variable linkers by Ring-Closing metathesis and their photophysical and DNA repeat binding properties
Mukherjee S, et al.
Chemistry?A European Journal , 23, 11385-11396 (2017)
Chemoselective esterification and amidation of carboxylic acids with imidazole carbamates and ureas
Heller ST and Sarpong R
Organic Letters, 12(20), 4572-4575 (2010)
相关内容
Professor Heller's research focuses on mild acylation reactions using carbonylimidazole-derived reagents.
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