762873
无水氯化铬(Ⅱ)
AnhydroBeads™, −10 mesh, 99.99% trace metals basis
别名:
二氯化铬, 氯化亚铬
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关于此项目
线性分子式:
CrCl2
化学文摘社编号:
分子量:
122.90
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23
等级
synthesis grade
质量水平
产品线
AnhydroBeads™
方案
99.99% trace metals basis
表单
beads
反应适用性
core: chromium
杂质
≤150.0 ppm Trace Metal Analysis
粒径
−10 mesh
mp
824 °C (lit.)
密度
2.9 g/mL at 25 °C (lit.)
应用
electroplating
material synthesis precursor
SMILES字符串
Cl[Cr]Cl
InChI
1S/2ClH.Cr/h2*1H;/q;;+2/p-2
InChI key
XBWRJSSJWDOUSJ-UHFFFAOYSA-L
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应用
在氢作用下与其他金属卤化物气相共还原生成细分的金属互化物，它们可用作具有有效的热电性、磁性和抗氧化性的结构材料或化合物。
Anhydrous chromium chloride is an important precursor for the low temperature synthesis of anhydrous metal sulfides, nitrides, phosphides, etc. It is also an important precursor for the synthesis of chromium containing mixed metal complexes; example lithium chromium chloride (Li2CrCl4), which shows rapid lithium ion conduction.
Anhydrous chromium chloride finds applications as catalysts, chromizing ferrous metals, steel, etc. The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties.
Chromium chloride powder is air and water sensitive. Beads have lower surface area and pour easily.
Anhydrous chromium chloride finds applications as catalysts, chromizing ferrous metals, steel, etc. The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties.
Chromium chloride powder is air and water sensitive. Beads have lower surface area and pour easily.
法律信息
AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC
警示用语：
Warning
危险声明
预防措施声明
危险分类
Acute Tox. 4 Oral
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Liliana Viciu et al.
Inorganic chemistry, 41(13), 3385-3388 (2002-06-25)
A new series of transition-metal oxyhalides (MCl)LaNb(2)O(7) (M = Cr, Mn, Fe, Co) have been prepared by a simple topochemical route. Layered perovskite hosts (ALaNb(2)O(7), A = Li, Na, K or Rb) were reacted with the corresponding anhydrous metal halides
Martin, M. J.; et al.
Inorganic Chemistry, 27, 2804-2804 (1988)
Zehui Zhang et al.
Bioresource technology, 102(4), 3970-3972 (2010-12-28)
Production of 5-hydroxymethylfurfural (HMF) from glucose was studied in ionic liquids in the presence of hydroxyapatite supported chromium chloride (Cr-HAP) using oil-bath heating and microwave irradiation (MI). Compared with oil-bath heating, the MI way obviously increased HMF yield and reduced
Zhongshun Yuan et al.
Carbohydrate research, 346(13), 2019-2023 (2011-07-09)
Efficient conversion of glucose to 5-hydroxymethyl furfural (5-HMF), a platform chemical for fuels and materials, was achieved using CrCl(2) or CrCl(3) as the catalysts with inexpensive co-catalysts and solvents including halide salts in dimethyl sulfoxide (DMSO) and several ionic liquids.
Min J Kwon et al.
Life sciences, 87(13-14), 401-404 (2010-08-21)
it has been suggested that Chromium (Cr), one of the essential minerals, can be beneficial to type 2 diabetic patients because it lowers blood glucose levels by improving various steps in insulin action. A few studies reported that Cr might
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