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经验公式(希尔记法):
CeO2/Y2O3
化学文摘社编号:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23
MDL number:
产品名称
氧化钇掺杂的氧化铈(IV), nanopowder, yttria 20 mol %, <50 nm particle size (TEM), 99.9% trace metals basis
SMILES string
O=[Ce]=O.O=[Y]O[Y]=O
InChI
1S/Ce.5O.2Y
InChI key
XVLUKJGVKWVXMP-UHFFFAOYSA-N
assay
99.9% trace metals basis
form
nanopowder
composition
yttria, 20 mol %
greener alternative product characteristics
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
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particle size
<50 nm (TEM)
greener alternative category
, Enabling
Quality Level
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Application
They are promising ceramic electrolytes for solid oxide fuel cells operating at low temperatures of 500-700°C (IT-SOFC). Doped ceria interlayers in between bulk yttria-stabilized zirconia electrolyte further enhance the performance of SOFCs.
YDC-20 can be used as an electrolyte in the fabrication of solid oxide fuel cells (SOFCs). A thin film of YDC-20 (~17.5 nm) effectively reduces the cathode/interfacial energy by 0.1 eV and increases the exchange current density by a factor of 4. It can be operated with a temperature range of 300° - 500°C.
General description
8mol% Yttria doped ceria may be prepared by carbonate coprecipitation technique. Yttria doped ceria exhibits high ionic conductivity, low activation energy and small grain boundary resistance. The effect of microstructure on the electrolytic properties was investigated in detail.
Cerium(IV) oxide-yttria doped (YDC-20) is an electrolytic material that is used as an alternative to zirconia-based electrolytes. Its properties include high ionic conductivity (0.01 S cm−1), electronic conductivity (3 S cm−1), enhanced electrode reactions, and high oxygen surface exchange coefficient.
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存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Sato, K.; et al.
Solid State Ionics, 180, 1220-1220 (2009)
sai; T.; Barnett; S. A.
Solid State Ionics, 98, 191-191 (1997)
Abazari; M.; et al.
Journal of the American Ceramic Society. American Ceramic Society, 95, 312-312 (2012)
Yttria-doped ceria anode for carbon-fueled solid oxide fuel cell
Kulkarni A, et al.
Journal of Solid State Electrochemistry, 19(2), 325-335 (2015)
Influence of nano-structural feature on electrolytic properties in Y2O3 doped CeO2 system.
Mori T, et al.
Science and Technology of Advanced Materials, 4(3), 213-220 (2003)
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